DOI: 10.1063/1.359317. Phase stability and transformations in pure and lanthanum modified lead zirconate ceramics

Phase stability and transformations in pure and lanthanum modified lead zirconate ceramics

10.1063/1.359317

Crossref journal-article

AIP Publishing

Journal of Applied Physics (317)

Abstract

Lanthanum modified lead zirconate with La to 8 at. % were prepared using mixed oxide method and followed by hot press sintering. The basic characterization included: dielectric spectroscopy, Sawyer–Tower polarization measurements, and temperature dependent selected area electron diffraction techniques. An intermediate rhombohedral ferroelectric phase (FER), characterized by square hysteresis loops, was found to exist in lead zirconate below the dielectric maximum. Strong 1/2{110} superlattice reflections associated with M-type oxygen octahedral rotation is found in the intermediate rhombohedral ferroelectric state. In addition, 1/x{110} incommensurate reflections were observed within a narrow temperature range between the FER phase and the low-temperature orthorhombic antiferroelectric state. With increasing La content, the temperature stability range of the incommensurate antiferroelectric phase was increased, at the expense of the FER phase. Incommensuration is suggested to result from a competition between ‘‘broken’’ dipolar and antiferroelectric sublattice interactions.

Bibliography

Dai, X., Xu, Z., & Viehland, D. (1995). Phase stability and transformations in pure and lanthanum modified lead zirconate ceramics. Journal of Applied Physics, 77(10), 5086â5094.

Authors 3

Xunhu Dai (first)
Z. Xu (additional)
Dwight Viehland (additional)

References 35 Referenced 36

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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 9:24 a.m.)
Deposited	1 year, 7 months ago (Feb. 2, 2024, 10:59 a.m.)
Indexed	2 months, 4 weeks ago (June 3, 2025, 1:28 a.m.)
Issued	30 years, 3 months ago (May 15, 1995)
Published	30 years, 3 months ago (May 15, 1995)
Published Print	30 years, 3 months ago (May 15, 1995)

Funders 0

None

BibTeX

@article{Dai_1995, title={Phase stability and transformations in pure and lanthanum modified lead zirconate ceramics}, volume={77}, ISSN={1089-7550}, url={http://dx.doi.org/10.1063/1.359317}, DOI={10.1063/1.359317}, number={10}, journal={Journal of Applied Physics}, publisher={AIP Publishing}, author={Dai, Xunhu and Xu, Z. and Viehland, Dwight}, year={1995}, month=may, pages={5086–5094} }

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