Abstract
We report the formation of band gaps in as-grown stacks of epitaxial graphene with opposite doping. Control of in-situ doping during carbon source molecular beam epitaxy growth on SiC was achieved by using different carbon sources. Doping heterostructures were grown by stacking n-type material from a C60 source on p-type material from a graphite filament source. Activation energies for the resistivity and carrier concentration indicated band gaps up to 200 meV. A photoconductivity threshold was observed in the range of the electrical activation energies. Band gap formation is attributed to electric fields induced by spatially separated ionized dopants of opposite charge.
Authors
12
- Jeongho Park (first)
- W. C. Mitchel (additional)
- Gail J. Brown (additional)
- Said Elhamri (additional)
- Lawrence Grazulis (additional)
- Howard E. Smith (additional)
- Shanee D. Pacley (additional)
- John J. Boeckl (additional)
- Kurt G. Eyink (additional)
- Shin Mou (additional)
- David H. Tomich (additional)
- John E. Hoelscher (additional)
References
14
Referenced
11
10.1038/nature05180
/ Nature (London) (2006)10.1103/PhysRevLett.98.206805
/ Phys. Rev. Lett. (2007)10.1103/PhysRevLett.96.086805
/ Phys. Rev. Lett. (2006)10.1038/nature08105
/ Nature (London) (2009)10.1103/PhysRevLett.99.216802
/ Phys. Rev. Lett. (2007)10.1103/PhysRevLett.102.256405
/ Phys. Rev. Lett. (2009)10.1126/science.1130681
/ Science (2006)10.1002/adma.201000756
/ Adv. Mater. (Weinheim, Ger.) (2010)10.1103/PhysRevB.82.081407
/ Phys. Rev. B (2010)10.1038/nmat2082
/ Nature Mater. (2008)10.1021/nl803698b
/ Nano Lett. (2009){'first-page': '80', 'volume-title': 'Electronic Properties of Doped Semiconductors', 'year': '1984', 'key': '2023070217012130700_c12'}
/ Electronic Properties of Doped Semiconductors (1984)10.1103/PhysRevB.74.165310
/ Phys. Rev. B (2006)10.1103/RevModPhys.81.109
/ Rev. Mod. Phys. (2009)
Dates
Type | When |
---|---|
Created | 14 years, 3 months ago (May 20, 2011, 7:39 p.m.) |
Deposited | 2 years, 2 months ago (July 2, 2023, 1:01 p.m.) |
Indexed | 1 month ago (July 30, 2025, 6:56 a.m.) |
Issued | 14 years, 3 months ago (May 16, 2011) |
Published | 14 years, 3 months ago (May 16, 2011) |
Published Online | 14 years, 3 months ago (May 17, 2011) |
Published Print | 14 years, 3 months ago (May 16, 2011) |
@article{Park_2011, title={Band gap formation in graphene by in-situ doping}, volume={98}, ISSN={1077-3118}, url={http://dx.doi.org/10.1063/1.3589364}, DOI={10.1063/1.3589364}, number={20}, journal={Applied Physics Letters}, publisher={AIP Publishing}, author={Park, Jeongho and Mitchel, W. C. and Brown, Gail J. and Elhamri, Said and Grazulis, Lawrence and Smith, Howard E. and Pacley, Shanee D. and Boeckl, John J. and Eyink, Kurt G. and Mou, Shin and Tomich, David H. and Hoelscher, John E.}, year={2011}, month=may }