DOI: 10.1063/1.3555336. PbO-deficient PbTiO3: Mass transport, structural effects and possibility for intrinsic screening of the ferroelectric polarization

PbO-deficient PbTiO3: Mass transport, structural effects and possibility for intrinsic screening of the ferroelectric polarization

10.1063/1.3555336

Crossref journal-article

AIP Publishing

Applied Physics Letters (317)

Abstract

Intrinsic solid solubility in the form of cation nonstoichiometry has been studied in PbO-deficient bulk PbTiO3 prepared by solid-state reaction. The unit cell distortion, or tetragonality c/a, decreases with increasing concentration of Pb and O vacancies across the solid solubility range. Mass transport during solid-state reaction and sintering is sensitive to the nominal stoichiometry of the system: Excess PbO promotes grain growth and densification while excess TiO2 yields coarsening and swelling. These findings are discussed with respect to thin film growth and screening of the ferroelectric polarization by point defect concentration gradients at epitaxial interfaces.

Bibliography

Selbach, S. M., Tybell, T., Einarsrud, M.-A., & Grande, T. (2011). PbO-deficient PbTiO3: Mass transport, structural effects and possibility for intrinsic screening of the ferroelectric polarization. Applied Physics Letters, 98(9).

Authors 4

Sverre M. Selbach (first)
Thomas Tybell (additional)
Mari-Ann Einarsrud (additional)
Tor Grande (additional)

References 23 Referenced 15

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10.1126/science.1098252 / Science (2004)
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10.1103/PhysRevLett.83.1347 / Phys. Rev. Lett. (1999)
10.1103/PhysRev.80.1105 / Phys. Rev. (1950)
10.1103/PhysRevLett.87.217601 / Phys. Rev. Lett. (2001)
10.1126/science.1092508 / Science (2004)
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10.1103/PhysRevLett.105.197602 / Phys. Rev. Lett. (2010)
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See supplementary material at http://dx.doi.org/10.1063/1.3555336 for XRD, DSC, SEM, and thermodynamic calculations. (10.1063/1.3555336)
10.1016/0025-5408(81)90178-1 / Mater. Res. Bull. (1981)
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10.1103/PhysRevLett.94.047603 / Phys. Rev. Lett. (2005)
10.1016/S0022-3697(99)00421-7 / J. Phys. Chem. Solids (2000)
10.1103/PhysRevLett.102.047601 / Phys. Rev. Lett. (2009)
10.1103/PhysRevLett.104.197601 / Phys. Rev. Lett. (2010)

Dates

Type	When
Created	14 years, 5 months ago (March 4, 2011, 11:37 a.m.)
Deposited	2 years, 1 month ago (July 14, 2023, 5:36 p.m.)
Indexed	3 weeks ago (Aug. 6, 2025, 9:03 a.m.)
Issued	14 years, 5 months ago (Feb. 28, 2011)
Published	14 years, 5 months ago (Feb. 28, 2011)
Published Online	14 years, 5 months ago (March 3, 2011)
Published Print	14 years, 5 months ago (Feb. 28, 2011)

Funders 0

None

BibTeX

@article{Selbach_2011, title={PbO-deficient PbTiO3: Mass transport, structural effects and possibility for intrinsic screening of the ferroelectric polarization}, volume={98}, ISSN={1077-3118}, url={http://dx.doi.org/10.1063/1.3555336}, DOI={10.1063/1.3555336}, number={9}, journal={Applied Physics Letters}, publisher={AIP Publishing}, author={Selbach, Sverre M. and Tybell, Thomas and Einarsrud, Mari-Ann and Grande, Tor}, year={2011}, month=feb }

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