Crossref journal-article
AIP Publishing
Journal of Applied Physics (317)
Abstract

Tetragonal La-modified lead zirconate titanate ceramics with a Zr/Ti ratio of 40/60 (x/40/60) with La contents (x) between 0 and 21 at. % were prepared by the mixed oxide method and were subsequently characterized using dielectric spectroscopy. Small La contents tended to diffuse the dielectric response in the temperature region around the phase transition, however, no distinct changes were observed in the paraelectric region. Compositions with intermediate La contents showed a thermally driven (spontaneous) transformation from a relaxor to a normal ferroelectric, i.e., micro-macro domain switching. Materials with a high La content exhibited typical relaxor ferroelectric behavior. The relative thermodynamic stability of the ensemble of micropolar regions is then discussed in reference to that of the long-range ferroelectric state.

Bibliography

Dai, X., DiGiovanni, A., & Viehland, D. (1993). Dielectric properties of tetragonal lanthanum modified lead zirconate titanate ceramics. Journal of Applied Physics, 74(5), 3399–3405.

Authors 3
  1. Xunhu Dai (first)
  2. A. DiGiovanni (additional)
  3. Dwight Viehland (additional)
References 28 Referenced 213
  1. {'key': '2024020211202157800_r1', 'first-page': '249', 'volume': '76', 'year': '1987', 'journal-title': 'Ferroelectrics'} / Ferroelectrics (1987)
  2. {'key': '2024020211202157800_r2', 'first-page': '1375', 'volume': '24', 'year': '1954', 'journal-title': 'Zh. Tekh. Fiz.'} / Zh. Tekh. Fiz. (1954)
  3. {'key': '2024020211202157800_r2a', 'first-page': '305', 'volume': '1', 'year': '1956', 'journal-title': 'Sov. Phys. Tech. Phys.'} / Sov. Phys. Tech. Phys. (1956)
  4. {'key': '2024020211202157800_r3', 'first-page': '1491', 'volume': '28', 'year': '1958', 'journal-title': 'Zh. Tekh. Fiz.'} / Zh. Tekh. Fiz. (1958)
  5. {'key': '2024020211202157800_r3a', 'first-page': '1380', 'volume': '3', 'year': '1958', 'journal-title': 'Sov. Phys. Tech. Phys.'} / Sov. Phys. Tech. Phys. (1958)
  6. {'key': '2024020211202157800_r4', 'first-page': '1', 'volume': '54', 'year': '1971', 'journal-title': 'J. Am. Ceram. Soc.'} / J. Am. Ceram. Soc. (1971)
  7. {'key': '2024020211202157800_r5', 'first-page': '84356', 'volume': '51', 'year': '1980', 'journal-title': 'J. Appl. Phys.'} / J. Appl. Phys. (1980)
  8. 10.1007/BF01106571 / J. Mater. Sci. (1986)
  9. 10.1007/BF00575371 / J. Mater. Sci. (1990)
  10. {'key': '2024020211202157800_r8', 'first-page': '829', 'volume': '54', 'year': '1990', 'journal-title': 'J. Mater. Res.'} / J. Mater. Res. (1990)
  11. 10.1111/j.1151-2916.1989.tb06180.x / J. Am. Ceram. Soc. (1989)
  12. 10.1080/00150198908018100 / Ferroelectrics (1989)
  13. {'key': '2024020211202157800_r11', 'first-page': '595', 'volume': '53', 'year': '1991', 'journal-title': 'J. Phys. Chem. Solids'} / J. Phys. Chem. Solids (1991)
  14. {'key': '2024020211202157800_r12', 'first-page': '259', 'volume': '104', 'year': '1990', 'journal-title': 'Ferroelectrics'} / Ferroelectrics (1990)
  15. {'key': '2024020211202157800_r13'}
  16. {'key': '2024020211202157800_r14', 'first-page': '17', 'volume': '14', 'year': '1980', 'journal-title': 'J. Phys. Chem. Solids'} / J. Phys. Chem. Solids (1980)
  17. {'key': '2024020211202157800_r15', 'first-page': '98', 'volume': '25', 'year': '1986', 'journal-title': 'Jpn. J. Appl. Phys.'} / Jpn. J. Appl. Phys. (1986)
  18. 10.1111/j.1151-2916.1973.tb12365.x / J. Am. Ceram. Soc. (1973)
  19. 10.1080/00150198708008208 / Ferroelectrics (1987)
  20. 10.1080/00018736000101229 / Adv. Phys. (1960)
  21. 10.1016/0022-3697(90)90025-B / J. Phys. Chem. Solids (1990)
  22. {'key': '2024020211202157800_r20', 'first-page': '465', 'volume': '33', 'year': '1970', 'journal-title': 'Phys. Status Solidi A'} / Phys. Status Solidi A (1970)
  23. 10.1103/PhysRevB.46.8003 / Phys. Rev. B (1992)
  24. 10.1103/PhysRevB.28.2527 / Phys. Rev. B (1983)
  25. 10.1103/PhysRevB.46.8013 / Phys. Rev. B (1992)
  26. 10.1063/1.332453 / J. Appl. Phys. (1983)
  27. 10.1016/0272-8842(82)90001-3 / Ceram. Int. (1982)
  28. 10.1080/00150198008009006 / Ferroelectrics (1980)
Dates
Type When
Created 23 years ago (July 26, 2002, 8:43 a.m.)
Deposited 1 year, 6 months ago (Feb. 2, 2024, 6:53 a.m.)
Indexed 1 week, 1 day ago (Aug. 12, 2025, 6:11 p.m.)
Issued 31 years, 11 months ago (Sept. 1, 1993)
Published 31 years, 11 months ago (Sept. 1, 1993)
Published Print 31 years, 11 months ago (Sept. 1, 1993)
Funders 0

None

@article{Dai_1993, title={Dielectric properties of tetragonal lanthanum modified lead zirconate titanate ceramics}, volume={74}, ISSN={1089-7550}, url={http://dx.doi.org/10.1063/1.354567}, DOI={10.1063/1.354567}, number={5}, journal={Journal of Applied Physics}, publisher={AIP Publishing}, author={Dai, Xunhu and DiGiovanni, A. and Viehland, Dwight}, year={1993}, month=sep, pages={3399–3405} }