DOI: 10.1063/1.353856. Dielectric polarizabilities of ions in oxides and fluorides

Dielectric polarizabilities of ions in oxides and fluorides

10.1063/1.353856

Crossref journal-article

AIP Publishing

Journal of Applied Physics (317)

Abstract

A set of 61 ion polarizabilities has been derived from the dielectric constants of 129 oxides and 25 fluorides using a least squares refinement technique in conjunction with the Clausius–Mosotti equation. These polarizabilities can be used to estimate mean dielectric constants of ‘‘well-behaved’’ compounds. They should be particularly useful in calculation of mean dielectric constants of compounds whose dielectric constants have not been determined. They can also be used as a framework for distinguishing unusual dielectric behavior from normal dielectric behavior where deviations can frequently be attributed to piezo- or ferroelectricity, conductivity (ionic or electronic), ‘‘rattling’’ or ‘‘compressed’’ cations with correspondingly high or low polarizabilities, or the presence of dipolar impurities. Deviations observed from calculated dielectric constants can be used to search for unusual physical behavior.

Bibliography

Shannon, R. D. (1993). Dielectric polarizabilities of ions in oxides and fluorides. Journal of Applied Physics, 73(1), 348â366.

Authors 1

R. D. Shannon (first)

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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 9:45 a.m.)
Deposited	1 year, 6 months ago (Feb. 4, 2024, 11:20 a.m.)
Indexed	50 minutes ago (Aug. 27, 2025, 1:28 p.m.)
Issued	32 years, 7 months ago (Jan. 1, 1993)
Published	32 years, 7 months ago (Jan. 1, 1993)
Published Print	32 years, 7 months ago (Jan. 1, 1993)

Funders 0

None

BibTeX

@article{Shannon_1993, title={Dielectric polarizabilities of ions in oxides and fluorides}, volume={73}, ISSN={1089-7550}, url={http://dx.doi.org/10.1063/1.353856}, DOI={10.1063/1.353856}, number={1}, journal={Journal of Applied Physics}, publisher={AIP Publishing}, author={Shannon, R. D.}, year={1993}, month=jan, pages={348–366} }

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