Abstract
Using directly interpretable atomic-resolution cross-sectional scanning transmission electron microscopy, we have investigated the structure of few-layer epitaxial graphene (EG) on 6H-SiC(0001). We show that the buried interface layer possesses a lower average areal density of carbon atoms than graphene, indicating that it is not a graphenelike sheet with the 63×63R30° structure. The EG interlayer spacings are found to be considerably larger than that of the bulk graphite and the surface of the SiC(0001) substrate, often treated as relaxed, is found to be strained. Discontinuity of the graphene layers above the SiC surface steps is observed, in contradiction with the commonly believed continuous coverage.
References
27
Referenced
31
10.1103/PhysRevLett.100.016602
/ Phys. Rev. Lett. (2008)10.1038/nmat1849
/ Nature Mater. (2007)10.1126/science.1125925
/ Science (2006)10.1088/0953-8984/20/32/323202
/ J. Phys.: Condens. Matter (2008)10.4028/www.scientific.net/MSF.556-557.525
/ Mater. Sci. Forum (2007)10.1103/PhysRevLett.99.076802
/ Phys. Rev. Lett. (2007)10.1103/PhysRevLett.99.126805
/ Phys. Rev. Lett. (2007)10.1103/PhysRevB.77.155303
/ Phys. Rev. B (2008)10.1103/PhysRevLett.100.176802
/ Phys. Rev. Lett. (2008)10.1103/PhysRevB.77.155426
/ Phys. Rev. B (2008)10.1088/0953-8984/21/13/134016
/ J. Phys.: Condens. Matter (2009)10.1103/PhysRevB.78.205424
/ Phys. Rev. B (2008)10.1016/j.cplett.2008.11.095
/ Chem. Phys. Lett. (2009)10.1016/j.carbon.2009.12.006
/ Carbon (2010)10.1103/PhysRevB.79.125437
/ Phys. Rev. B (2009)10.1088/0957-4484/20/44/445704
/ Nanotechnology (2009)10.1038/nmat2382
/ Nature Mater. (2009)10.1103/PhysRevB.80.041401
/ Phys. Rev. B (2009)10.1038/nnano.2008.280
/ Nat. Nanotechnol. (2008)10.1016/0304-3991(96)00020-4
/ Ultramicroscopy (1996)10.1016/0304-3991(93)90043-W
/ Ultramicroscopy (1993)- See supplementary material at http://dx.doi.org/10.1063/1.3517505 for detailed discussions on the structure and composition proposed for the buried interface by earlier studies.
10.1016/0304-3991(93)90046-Z
/ Ultramicroscopy (1993)10.1103/PhysRevLett.101.156801
/ Phys. Rev. Lett. (2008)10.1103/PhysRevB.80.121406
/ Phys. Rev. B (2009)10.1016/j.ssc.2007.04.023
/ Solid State Commun. (2007)10.1103/PhysRevB.81.195434
/ Phys. Rev. B (2010)
Dates
Type | When |
---|---|
Created | 14 years, 9 months ago (Nov. 17, 2010, 6:14 p.m.) |
Deposited | 2 years, 1 month ago (July 31, 2023, 5:07 a.m.) |
Indexed | 1 month ago (July 30, 2025, 6:56 a.m.) |
Issued | 14 years, 9 months ago (Nov. 15, 2010) |
Published | 14 years, 9 months ago (Nov. 15, 2010) |
Published Online | 14 years, 9 months ago (Nov. 17, 2010) |
Published Print | 14 years, 9 months ago (Nov. 15, 2010) |
@article{Weng_2010, title={Structure of few-layer epitaxial graphene on 6H-SiC(0001) at atomic resolution}, volume={97}, ISSN={1077-3118}, url={http://dx.doi.org/10.1063/1.3517505}, DOI={10.1063/1.3517505}, number={20}, journal={Applied Physics Letters}, publisher={AIP Publishing}, author={Weng, Xiaojun and Robinson, Joshua A. and Trumbull, Kathleen and Cavalero, Randall and Fanton, Mark A. and Snyder, David}, year={2010}, month=nov }