DOI: 10.1063/1.351228. Photoisomerization of azobenzene derivatives in polymeric thin films

Photoisomerization of azobenzene derivatives in polymeric thin films

10.1063/1.351228

Crossref journal-article

AIP Publishing

Journal of Applied Physics (317)

Abstract

The photoisomerization of disperse red 1 (DR1) in polymethylmethacrylate thin films is demonstrated by monitoring the refractive index variations by the attenuated total reflection method. Absorption spectrum measurements give a confirmation of this phenomenon. The kinetics of photoisomerization and of thermal relaxation are nonexponential. Some other molecules are studied. As in solution, azobenzene derivatives (N—N) produce reversible isomerization while dimethylaminonitrostilbene, a stilbene derivative (C—C), exhibits no thermal cis→trans relaxation.

Bibliography

Sekkat, Z., MorichÃ¨re, D., Dumont, M., Loucif-SaÃ¯bi, R., & Delaire, J. A. (1992). Photoisomerization of azobenzene derivatives in polymeric thin films. Journal of Applied Physics, 71(3), 1543â1545.

Authors 5

Z. Sekkat (first)
D. Morichère (additional)
M. Dumont (additional)
R. Loucif-Saïbi (additional)
J. A. Delaire (additional)

References 16 Referenced 129

10.1364/JOSAB.7.001239 / J. Opt. Soc. Am. B (1990)
10.1063/1.97184 / Appl. Phys. Lett. (1986)
10.1063/1.99785 / Appl. Phys. Lett. (1988)
10.1364/JOSAB.7.000842 / J. Opt. Soc. Am. B (1990)
10.1364/JOSAB.6.000733 / J. Opt. Soc. Am. (1989)
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{'key': '2024020414595130600_r5', 'first-page': '1447', 'volume': '17', 'year': '1983', 'journal-title': 'Macromolecules'} / Macromolecules (1983)
10.1021/ma00180a012 / Macromolecules (1988)
10.1063/1.104393 / Appl. Phys. Lett. (1991)
{'key': '2024020414595130600_r7'}
10.1016/0030-4018(89)90023-0 / Opt. Commun. (1989)
{'key': '2024020414595130600_r9'}
10.1364/OL.8.000324 / Opt. Lett. (1983)
10.1021/j100674a023 / J. Phys. Chem. (1971)
10.1021/ja01017a002 / J. Am. Chem. Soc. (1968)
{'key': '2024020414595130600_r12a'}

Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 8:43 a.m.)
Deposited	1 year, 7 months ago (Feb. 4, 2024, 10 a.m.)
Indexed	3 months, 2 weeks ago (May 18, 2025, 2:20 a.m.)
Issued	33 years, 7 months ago (Feb. 1, 1992)
Published	33 years, 7 months ago (Feb. 1, 1992)
Published Print	33 years, 7 months ago (Feb. 1, 1992)

Funders 0

None

BibTeX

@article{Sekkat_1992, title={Photoisomerization of azobenzene derivatives in polymeric thin films}, volume={71}, ISSN={1089-7550}, url={http://dx.doi.org/10.1063/1.351228}, DOI={10.1063/1.351228}, number={3}, journal={Journal of Applied Physics}, publisher={AIP Publishing}, author={Sekkat, Z. and Morichère, D. and Dumont, M. and Loucif-Saïbi, R. and Delaire, J. A.}, year={1992}, month=feb, pages={1543–1545} }

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