DOI: 10.1063/1.3505045. Polarized Raman spectroscopic study of relaxed high density amorphous ices under pressure

Polarized Raman spectroscopic study of relaxed high density amorphous ices under pressure

10.1063/1.3505045

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

We have made high density amorphous ice (HDA) by the pressure-induced amorphization of hexagonal ice at 77 K and measured the volume change on isobaric heating in a pressure range between 0.1 and 1.5 GPa. The volume of HDA on heating below ∼0.35 GPa increases, while the volume of HDA on heating above ∼0.35 GPa decreases. The polarized OH-stretching Raman spectra of the relaxed HDAs are compared with that of the unannealed HDA. The relaxed HDAs are prepared at 0.2 GPa at 130 K and 1.5 GPa at 160 K. It is found that the relatively strong totally symmetric OH-stretching vibration mode around 3100 cm−1 exists in the depolarized reduced Raman spectrum χVH″ of the unannealed HDA and that its intensity rapidly decreases by relaxation. The χVH″ profiles of the relaxed HDA are similar to those of liquid water. These results indicate that the HDA reaches a nearly equilibrium state by annealing and the intrinsic state of HDA relates to a liquid state. The pressure-volume curve of the relaxed HDA at 140 K seems to be smooth in the pressure range below 1.5 GPa.

Bibliography

Suzuki, Y., & Tominaga, Y. (2010). Polarized Raman spectroscopic study of relaxed high density amorphous ices under pressure. The Journal of Chemical Physics, 133(16).

Authors 2

Yoshiharu Suzuki (first)
Yasunori Tominaga (additional)

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Dates

Type	When
Created	14 years, 10 months ago (Oct. 26, 2010, 10:04 a.m.)
Deposited	2 years, 1 month ago (July 1, 2023, 11:22 p.m.)
Indexed	1 month ago (July 30, 2025, 6:55 a.m.)
Issued	14 years, 10 months ago (Oct. 25, 2010)
Published	14 years, 10 months ago (Oct. 25, 2010)
Published Online	14 years, 10 months ago (Oct. 25, 2010)
Published Print	14 years, 10 months ago (Oct. 28, 2010)

Funders 0

None

BibTeX

@article{Suzuki_2010, title={Polarized Raman spectroscopic study of relaxed high density amorphous ices under pressure}, volume={133}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.3505045}, DOI={10.1063/1.3505045}, number={16}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Suzuki, Yoshiharu and Tominaga, Yasunori}, year={2010}, month=oct }

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