DOI: 10.1063/1.3487999. Volume of supercooled water under pressure and the liquid-liquid critical point

Volume of supercooled water under pressure and the liquid-liquid critical point

10.1063/1.3487999

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The volume of water (H2O) was obtained at about 200–275 K and 40–400 MPa by using emulsified water. The plot of volume against temperature showed slightly concave-downward curvature at pressures higher than ≈200 MPa. This is compatible with the liquid-liquid critical-point hypothesis, but hardly with the singularity-free scenario. When the critical point is assumed to exist at ≈50 MPa and ≈223 K, the experimental volume and the derived compressibility are qualitatively described by the modified Fuentevilla–Anisimov scaling equation.

Bibliography

Mishima, O. (2010). Volume of supercooled water under pressure and the liquid-liquid critical point. The Journal of Chemical Physics, 133(14).

Authors 1

Osamu Mishima (first)

References 29 Referenced 171

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{'key': '2023070321193669800_c24', 'first-page': '411', 'volume': '455', 'year': '1997', 'journal-title': 'Mater. Res. Soc. Symp. Proc.'} / Mater. Res. Soc. Symp. Proc. (1997)
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See supplementary material at http://dx.doi.org/10.1063/1.3487999 for the rotation of the three-dimensional figures and the numerical values (Fig. 1).
10.1039/b510168a / Phys. Chem. Chem. Phys. (2006)

Dates

Type	When
Created	14 years, 10 months ago (Oct. 11, 2010, 6:13 p.m.)
Deposited	2 years, 2 months ago (July 3, 2023, 8:07 p.m.)
Indexed	1 week, 2 days ago (Aug. 27, 2025, 12:33 p.m.)
Issued	14 years, 10 months ago (Oct. 11, 2010)
Published	14 years, 10 months ago (Oct. 11, 2010)
Published Online	14 years, 10 months ago (Oct. 11, 2010)
Published Print	14 years, 10 months ago (Oct. 14, 2010)

Funders 0

None

BibTeX

@article{Mishima_2010, title={Volume of supercooled water under pressure and the liquid-liquid critical point}, volume={133}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.3487999}, DOI={10.1063/1.3487999}, number={14}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Mishima, Osamu}, year={2010}, month=oct }

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