DOI: 10.1063/1.335262. Pressure concentration isotherms of thin films of the palladium-hydrogen system as modified by film thickness, hydrogen cycling, and stress

Pressure concentration isotherms of thin films of the palladium-hydrogen system as modified by film thickness, hydrogen cycling, and stress

10.1063/1.335262

Crossref journal-article

AIP Publishing

Journal of Applied Physics (317)

Abstract

We describe the results of a novel adaptation of the volumetric technique to measurement of the pressure concentration isotherms for thin films of the palladium-hydrogen system. The isotherm shapes are comparable to bulk being steep in the alpha and beta phases and flat in the mixed phase region. However, it is noted that the concentration onset of the beta phase is smaller than bulk and drops markedly for thicknesses less than 670 Å. Comparison is made with quartz crystal microbalance results. We find a thickness dependence to the number of absorption-desorption cycles required to obtain reproducible isotherms.

Bibliography

Lee, M.-W., & Glosser, R. (1985). Pressure concentration isotherms of thin films of the palladium-hydrogen system as modified by film thickness, hydrogen cycling, and stress. Journal of Applied Physics, 57(12), 5236â5239.

Authors 2

Ming-Way Lee (first)
R. Glosser (additional)

References 13 Referenced 47

10.1016/0022-5088(83)90360-0 / J. Less-Common Metals (1983)
10.1016/0250-6874(81)80018-2 / Sensors and Actuators (1981)
10.1063/1.334046 / J. Appl. Phys. (1984)
10.1088/0022-3727/12/10/002 / J. Phys. D (1979)
10.1016/0022-5088(80)90077-6 / J. Less-Common Metals (1980)
{'key': '2024020504275028800_r5'}
10.1088/0305-4608/13/2/001 / J. Phys. F (1983)
{'key': '2024020504275028800_r7', 'first-page': '225', 'volume': 'NF88', 'year': '1974', 'journal-title': 'Z. Phys. Chem.'} / Z. Phys. Chem. (1974)
{'key': '2024020504275028800_r8'}
10.1002/bbpc.19640680303 / Ber. Bunsenges. Phys. Chem. (1964)
{'key': '2024020504275028800_r10', 'first-page': '109', 'volume': 'NF114', 'year': '1979', 'journal-title': 'Z. Phys. Chem.'} / Z. Phys. Chem. (1979)
10.1002/bbpc.19730770112 / Ber. Bunsenges. Phys. Chem. (1973)
{'key': '2024020504275028800_r12'}

Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 9:05 a.m.)
Deposited	1 year, 7 months ago (Feb. 4, 2024, 11:28 p.m.)
Indexed	3 months, 2 weeks ago (May 22, 2025, 12:23 a.m.)
Issued	40 years, 2 months ago (June 15, 1985)
Published	40 years, 2 months ago (June 15, 1985)
Published Print	40 years, 2 months ago (June 15, 1985)

Funders 0

None

BibTeX

@article{Lee_1985, title={Pressure concentration isotherms of thin films of the palladium-hydrogen system as modified by film thickness, hydrogen cycling, and stress}, volume={57}, ISSN={1089-7550}, url={http://dx.doi.org/10.1063/1.335262}, DOI={10.1063/1.335262}, number={12}, journal={Journal of Applied Physics}, publisher={AIP Publishing}, author={Lee, Ming-Way and Glosser, R.}, year={1985}, month=jun, pages={5236–5239} }

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