DOI: 10.1063/1.3266521. The effect of hydrogen charging on Ln-based amorphous materials

The effect of hydrogen charging on Ln-based amorphous materials

10.1063/1.3266521

Crossref journal-article

AIP Publishing

Applied Physics Letters (317)

Abstract

In present work, the effects of hydrogen charging on Ln-based (Ln=La,Ce) bulk-metallic glasses (BMG) are studied. The (La0.5Ce0.5)65Al10Co25 were charged with hydrogen by an electrochemical method in an alkali solution. The hydrogen concentration in the sample after a 36 h charge can reach as high as 1286 w-ppm. With the presence of hydrogen atoms, the hardness of specimen increased by 80% compared to the as-cast samples. The structural evolution of the amorphous matrix due to the hydrogen-uptake process was investigated by the high-energy x-ray scattering technique. The sample surface was crystallized after hydrogen charging. X-ray diffraction measurements revealed broad crystalline peaks superimposed on an amorphous-scattering pattern. The crystalline phase grew from the surface to at least one hundred microns deep into the amorphous matrix. The atomic arrangements of both amorphous and crystalline phases were characterized by the atomic pair-distribution function.

Bibliography

Chuang, C. P., Huang, J. H., Dmowski, W., Liaw, P. K., Li, R., Zhang, T., & Ren, Y. (2009). The effect of hydrogen charging on Ln-based amorphous materials. Applied Physics Letters, 95(24).

Authors 7

C. P. Chuang (first)
J. H. Huang (additional)
W. Dmowski (additional)
P. K. Liaw (additional)
R. Li (additional)
T. Zhang (additional)
Y. Ren (additional)

References 14 Referenced 8

10.2320/matertrans1989.34.1234 / Mater. Trans., JIM (1993)
10.1063/1.119610 / Appl. Phys. Lett. (1997)
10.1016/j.scriptamat.2005.09.051 / Scr. Mater. (2006)
{'volume-title': 'Bulk Metallic Glasses', 'year': '2007', 'author': 'Miller', 'key': '2023070217125037100_c4'} / Bulk Metallic Glasses by Miller (2007)
10.1016/j.jallcom.2006.07.138 / J. Alloys Compd. (2007)
10.1016/j.memsci.2006.09.014 / J. Membr. Sci. (2006)
10.1016/j.memsci.2006.12.049 / J. Membr. Sci. (2007)
10.1088/0953-8984/21/11/115402 / J. Phys. Condens. Matter (2009)
{'key': '2023070217125037100_c9', 'first-page': '639', 'volume-title': 'Hydrogen Effects on Material Behavior, TMS', 'author': 'Moody', 'year': '1990'} / Hydrogen Effects on Material Behavior, TMS by Moody (1990)
10.1016/j.actamat.2007.02.026 / Acta Mater. (2007)
10.1021/ic50044a018 / Inorg. Chem. (1966)
10.1088/0022-3719/7/14/005 / J. Phys. C (1974)
10.1016/0022-5088(85)90311-X / J. Less-Common Met. (1985)
{'volume-title': 'Underneath the Bragg Peaks: Structural Analysis of Complex Materials', 'year': '2003', 'key': '2023070217125037100_c14'} / Underneath the Bragg Peaks: Structural Analysis of Complex Materials (2003)

Dates

Type	When
Created	15 years, 8 months ago (Dec. 14, 2009, 6:48 p.m.)
Deposited	2 years, 2 months ago (July 2, 2023, 1:12 p.m.)
Indexed	1 month ago (July 30, 2025, 6:54 a.m.)
Issued	15 years, 8 months ago (Dec. 14, 2009)
Published	15 years, 8 months ago (Dec. 14, 2009)
Published Online	15 years, 8 months ago (Dec. 14, 2009)
Published Print	15 years, 8 months ago (Dec. 14, 2009)

Funders 0

None

BibTeX

@article{Chuang_2009, title={The effect of hydrogen charging on Ln-based amorphous materials}, volume={95}, ISSN={1077-3118}, url={http://dx.doi.org/10.1063/1.3266521}, DOI={10.1063/1.3266521}, number={24}, journal={Applied Physics Letters}, publisher={AIP Publishing}, author={Chuang, C. P. and Huang, J. H. and Dmowski, W. and Liaw, P. K. and Li, R. and Zhang, T. and Ren, Y.}, year={2009}, month=dec }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        7,
        30
      ]
    ],
    "date-time": "2025-07-30T10:54:05Z",
    "timestamp": 1753872845545,
    "version": "3.41.2"
  },
  "reference-count": 14,
  "publisher": "AIP Publishing",
  "issue": "24",
  "content-domain": {
    "domain": [
      "pubs.aip.org"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        2009,
        12,
        14
      ]
    ]
  },
  "abstract": "<jats:p>In present work, the effects of hydrogen charging on Ln-based (Ln=La,Ce) bulk-metallic glasses (BMG) are studied. The (La0.5Ce0.5)65Al10Co25 were charged with hydrogen by an electrochemical method in an alkali solution. The hydrogen concentration in the sample after a 36 h charge can reach as high as 1286 w-ppm. With the presence of hydrogen atoms, the hardness of specimen increased by 80% compared to the as-cast samples. The structural evolution of the amorphous matrix due to the hydrogen-uptake process was investigated by the high-energy x-ray scattering technique. The sample surface was crystallized after hydrogen charging. X-ray diffraction measurements revealed broad crystalline peaks superimposed on an amorphous-scattering pattern. The crystalline phase grew from the surface to at least one hundred microns deep into the amorphous matrix. The atomic arrangements of both amorphous and crystalline phases were characterized by the atomic pair-distribution function.</jats:p>",
  "DOI": "10.1063/1.3266521",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2009,
        12,
        14
      ]
    ],
    "date-time": "2009-12-14T23:48:57Z",
    "timestamp": 1260834537000
  },
  "update-policy": "https://doi.org/10.1063/aip-crossmark-policy-page",
  "source": "Crossref",
  "is-referenced-by-count": 8,
  "title": "The effect of hydrogen charging on Ln-based amorphous materials",
  "prefix": "10.1063",
  "volume": "95",
  "author": [
    {
      "given": "C. P.",
      "family": "Chuang",
      "sequence": "first",
      "affiliation": [
        {
          "name": "National Tsing-Hua University 1 Department of Engineering and System Science, , Hsin-Chu 300, Taiwan"
        },
        {
          "name": "University of Tennessee 2 Department of Materials Science and Engineering, , Knoxville, Tennessee 37996, USA"
        }
      ]
    },
    {
      "given": "J. H.",
      "family": "Huang",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "National Tsing-Hua University 1 Department of Engineering and System Science, , Hsin-Chu 300, Taiwan"
        }
      ]
    },
    {
      "given": "W.",
      "family": "Dmowski",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "University of Tennessee 2 Department of Materials Science and Engineering, , Knoxville, Tennessee 37996, USA"
        }
      ]
    },
    {
      "given": "P. K.",
      "family": "Liaw",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "University of Tennessee 2 Department of Materials Science and Engineering, , Knoxville, Tennessee 37996, USA"
        }
      ]
    },
    {
      "given": "R.",
      "family": "Li",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Beijing University of Aeronautics and Astronautics 3 Department of Materials Science and Engineering, , Beijing 100083, People's Republic of China"
        }
      ]
    },
    {
      "given": "T.",
      "family": "Zhang",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Beijing University of Aeronautics and Astronautics 3 Department of Materials Science and Engineering, , Beijing 100083, People's Republic of China"
        }
      ]
    },
    {
      "given": "Y.",
      "family": "Ren",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Argonne National Laboratory 4 Advanced Photon Source, , Chicago, Illinois 60439, USA"
        }
      ]
    }
  ],
  "member": "317",
  "published-online": {
    "date-parts": [
      [
        2009,
        12,
        14
      ]
    ]
  },
  "reference": [
    {
      "key": "2023070217125037100_c1",
      "doi-asserted-by": "crossref",
      "first-page": "1234",
      "DOI": "10.2320/matertrans1989.34.1234",
      "volume": "34",
      "year": "1993",
      "journal-title": "Mater. Trans., JIM"
    },
    {
      "key": "2023070217125037100_c2",
      "doi-asserted-by": "publisher",
      "first-page": "476",
      "DOI": "10.1063/1.119610",
      "volume": "71",
      "year": "1997",
      "journal-title": "Appl. Phys. Lett."
    },
    {
      "key": "2023070217125037100_c3",
      "doi-asserted-by": "publisher",
      "first-page": "321",
      "DOI": "10.1016/j.scriptamat.2005.09.051",
      "volume": "54",
      "year": "2006",
      "journal-title": "Scr. Mater."
    },
    {
      "volume-title": "Bulk Metallic Glasses",
      "year": "2007",
      "author": "Miller",
      "key": "2023070217125037100_c4"
    },
    {
      "key": "2023070217125037100_c5",
      "doi-asserted-by": "publisher",
      "first-page": "152",
      "DOI": "10.1016/j.jallcom.2006.07.138",
      "volume": "442",
      "year": "2007",
      "journal-title": "J. Alloys Compd."
    },
    {
      "key": "2023070217125037100_c6",
      "doi-asserted-by": "publisher",
      "first-page": "30",
      "DOI": "10.1016/j.memsci.2006.09.014",
      "volume": "285",
      "year": "2006",
      "journal-title": "J. Membr. Sci."
    },
    {
      "key": "2023070217125037100_c7",
      "doi-asserted-by": "publisher",
      "first-page": "126",
      "DOI": "10.1016/j.memsci.2006.12.049",
      "volume": "291",
      "year": "2007",
      "journal-title": "J. Membr. Sci."
    },
    {
      "key": "2023070217125037100_c8",
      "doi-asserted-by": "publisher",
      "first-page": "115402",
      "DOI": "10.1088/0953-8984/21/11/115402",
      "volume": "21",
      "year": "2009",
      "journal-title": "J. Phys. Condens. Matter"
    },
    {
      "key": "2023070217125037100_c9",
      "first-page": "639",
      "volume-title": "Hydrogen Effects on Material Behavior, TMS",
      "author": "Moody",
      "year": "1990"
    },
    {
      "key": "2023070217125037100_c10",
      "doi-asserted-by": "publisher",
      "first-page": "3719",
      "DOI": "10.1016/j.actamat.2007.02.026",
      "volume": "55",
      "year": "2007",
      "journal-title": "Acta Mater."
    },
    {
      "key": "2023070217125037100_c11",
      "doi-asserted-by": "publisher",
      "first-page": "1719",
      "DOI": "10.1021/ic50044a018",
      "volume": "5",
      "year": "1966",
      "journal-title": "Inorg. Chem."
    },
    {
      "key": "2023070217125037100_c12",
      "doi-asserted-by": "publisher",
      "first-page": "2409",
      "DOI": "10.1088/0022-3719/7/14/005",
      "volume": "7",
      "year": "1974",
      "journal-title": "J. Phys. C"
    },
    {
      "key": "2023070217125037100_c13",
      "doi-asserted-by": "publisher",
      "first-page": "107",
      "DOI": "10.1016/0022-5088(85)90311-X",
      "volume": "110",
      "year": "1985",
      "journal-title": "J. Less-Common Met."
    },
    {
      "volume-title": "Underneath the Bragg Peaks: Structural Analysis of Complex Materials",
      "year": "2003",
      "key": "2023070217125037100_c14"
    }
  ],
  "container-title": "Applied Physics Letters",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.aip.org/aip/apl/article-pdf/doi/10.1063/1.3266521/14422507/241901_1_online.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://pubs.aip.org/aip/apl/article-pdf/doi/10.1063/1.3266521/14422507/241901_1_online.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2023,
        7,
        2
      ]
    ],
    "date-time": "2023-07-02T17:12:59Z",
    "timestamp": 1688317979000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.aip.org/apl/article/95/24/241901/325633/The-effect-of-hydrogen-charging-on-Ln-based"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        2009,
        12,
        14
      ]
    ]
  },
  "references-count": 14,
  "journal-issue": {
    "issue": "24",
    "published-print": {
      "date-parts": [
        [
          2009,
          12,
          14
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.3266521",
  "relation": {},
  "ISSN": [
    "0003-6951",
    "1077-3118"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        2009,
        12,
        14
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        2009,
        12,
        14
      ]
    ]
  },
  "article-number": "241901"
}