Abstract
We have characterized the electrical transport properties of neutron-transmutation-doped polycrystalline silicon. Zero-bias measurements of resistance have been made as a function of temperature on both bulk specimens and individual grain boundaries in this material. Below a doping level of ∼2×1015 phosphorus/cm3, the bulk resistance has a nearly Arrhenius behavior with an activation energy of ∼0.55 eV; above this donor concentration the resistivity is markedly curved on an Arrhenius plot with values of slope which decrease with decreasing temperature. Potential probe measurements show that a large spread in grain-boundary impedances exist in these higher-doped specimens. We compare our data to theoretical expressions for current flow across grain-boundary potential barriers and good agreement is observed; these comparisons indicate that the largest grain-boundary state densities observed in our samples consist of ∼6×1011 available single-electron-states/cm2 located within ∼0.2 eV from the center of the forbidden gap. The chemical potential of these grain-boundary regions is found to lie at midgap, in agreement with previous data on thin-film polycrystalline silicon. We note that the considerably higher orientation-independent state densities found in thin-film polycrystalline silicon contrasts strongly with the present data and suggest the presence of serious contamination effects in previously studied material.
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Dates
Type | When |
---|---|
Created | 22 years, 6 months ago (Feb. 14, 2003, 4:46 p.m.) |
Deposited | 1 year, 6 months ago (Feb. 4, 2024, 3:52 p.m.) |
Indexed | 1 month, 1 week ago (July 25, 2025, 6:22 a.m.) |
Issued | 47 years, 2 months ago (July 1, 1978) |
Published | 47 years, 2 months ago (July 1, 1978) |
Published Print | 47 years, 2 months ago (July 1, 1978) |
@article{Seager_1978, title={Zero-bias resistance of grain boundaries in neutron-transmutation-doped polycrystalline silicon}, volume={49}, ISSN={1089-7550}, url={http://dx.doi.org/10.1063/1.325394}, DOI={10.1063/1.325394}, number={7}, journal={Journal of Applied Physics}, publisher={AIP Publishing}, author={Seager, C. H. and Castner, T. G.}, year={1978}, month=jul, pages={3879–3889} }