DOI: 10.1063/1.3243314. Temperature and density dependence of the structural relaxation time in water by inelastic ultraviolet scattering

Temperature and density dependence of the structural relaxation time in water by inelastic ultraviolet scattering

10.1063/1.3243314

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The density and temperature dependence of the structural relaxation time (τ) in water was determined by inelastic ultraviolet scattering spectroscopy in the thermodynamic range (P=1–4000 bars, T=253–323 K), where several water anomalies take place. We observed an activation (Arrhenius) temperature dependence of τ at constant density and a monotonic density decrease at constant temperature. The latter trend was accounted for by introducing a density-dependent activation entropy associated to water local structure. The combined temperature and density behavior of τ indicates that differently from previous results, in the probed thermodynamic range, the relaxation process is ruled by a density-dependent activation Helmholtz free energy rather than a simple activation energy. Finally, the extrapolation of the observed phenomenology at lower temperature suggests a substantial agreement with the liquid-liquid phase transition hypothesis.

Bibliography

Bencivenga, F., Cimatoribus, A., Gessini, A., Izzo, M. G., & Masciovecchio, C. (2009). Temperature and density dependence of the structural relaxation time in water by inelastic ultraviolet scattering. The Journal of Chemical Physics, 131(14).

Authors 5

F. Bencivenga (first)
A. Cimatoribus (additional)
A. Gessini (additional)
M. G. Izzo (additional)
C. Masciovecchio (additional)

References 65 Referenced 30

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Dates

Type	When
Created	15 years, 10 months ago (Oct. 8, 2009, 7:55 p.m.)
Deposited	2 years, 1 month ago (June 26, 2023, 12:26 a.m.)
Indexed	2 weeks, 4 days ago (Aug. 6, 2025, 8:41 a.m.)
Issued	15 years, 10 months ago (Oct. 8, 2009)
Published	15 years, 10 months ago (Oct. 8, 2009)
Published Online	15 years, 10 months ago (Oct. 8, 2009)
Published Print	15 years, 10 months ago (Oct. 14, 2009)

Funders 0

None

BibTeX

@article{Bencivenga_2009, title={Temperature and density dependence of the structural relaxation time in water by inelastic ultraviolet scattering}, volume={131}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.3243314}, DOI={10.1063/1.3243314}, number={14}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Bencivenga, F. and Cimatoribus, A. and Gessini, A. and Izzo, M. G. and Masciovecchio, C.}, year={2009}, month=oct }

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