Abstract
The impact of n-doping on the electronic structure of two organic-organic heterojunctions (OOH) is investigated with ultraviolet photoemission spectroscopy. The two OOHs have a type II staggered gap configuration corresponding to donor-acceptor pairs applicable to photovoltaic cells. Both molecular top acceptor layers have large electron affinity, which leads to electron transfer from the donor layer. The result is a significant interface dipole (Δ∼0.4–0.6eV) between the two molecular films, at both undoped and doped interfaces, consistent with a stronger interaction between molecular constituents than in wide, largely overlapping, band gap OOHs.
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Dates
Type | When |
---|---|
Created | 16 years, 2 months ago (June 23, 2009, 6:33 p.m.) |
Deposited | 2 years, 1 month ago (Aug. 2, 2023, 5:59 a.m.) |
Indexed | 6 days, 11 hours ago (Aug. 29, 2025, 6:43 a.m.) |
Issued | 16 years, 2 months ago (June 15, 2009) |
Published | 16 years, 2 months ago (June 15, 2009) |
Published Online | 16 years, 2 months ago (June 23, 2009) |
Published Print | 16 years, 2 months ago (June 15, 2009) |
@article{Zhao_2009, title={Charge transfer at n-doped organic-organic heterojunctions}, volume={105}, ISSN={1089-7550}, url={http://dx.doi.org/10.1063/1.3153962}, DOI={10.1063/1.3153962}, number={12}, journal={Journal of Applied Physics}, publisher={AIP Publishing}, author={Zhao, Wei and Kahn, Antoine}, year={2009}, month=jun }