DOI: 10.1063/1.3152783. Crystal and electronic structure of lithiated nanosized rutile TiO2 by electron diffraction and electron energy-loss spectroscopy

Crystal and electronic structure of lithiated nanosized rutile TiO2 by electron diffraction and electron energy-loss spectroscopy

10.1063/1.3152783

Crossref journal-article

AIP Publishing

Applied Physics Letters (317)

Abstract

The crystal and electronic structure of the lithiated nanosized rutile TiO2 were studied using electron diffraction and electron energy-loss spectroscopy (EELS) in a transmission electron microscopy. EELS reveals the Li K-edge at the energy-loss position of ∼61 eV. After lithiation, the t2g-eg crystal-field splitting on both Ti L2,3-edge and O K-edge decreases, the O K-edge shifts toward a higher energy-loss position and the separation between the pre-edge peak and main peak on the O K-edge decreases, suggesting that the lithiation of rutile TiO2 was accompanied by the reduction in Ti ion, indicating a charge transfer from Li to Ti.

Bibliography

Wang, C. M., Yang, Z. G., Thevuthasan, S., Liu, J., Baer, D. R., Choi, D., Wang, D. H., Zhang, J. G., Saraf, L. V., & Nie, Z. M. (2009). Crystal and electronic structure of lithiated nanosized rutile TiO2 by electron diffraction and electron energy-loss spectroscopy. Applied Physics Letters, 94(23).

Authors 10

C. M. Wang (first)
Z. G. Yang (additional)
S. Thevuthasan (additional)
J. Liu (additional)
D. R. Baer (additional)
D. Choi (additional)
D. H. Wang (additional)
J. G. Zhang (additional)
L. V. Saraf (additional)
Z. M. Nie (additional)

References 20 Referenced 24

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Dates

Type	When
Created	16 years, 2 months ago (June 11, 2009, 6:13 p.m.)
Deposited	2 years, 1 month ago (July 2, 2023, 6:04 p.m.)
Indexed	5 days, 17 hours ago (Aug. 21, 2025, 1:45 p.m.)
Issued	16 years, 2 months ago (June 8, 2009)
Published	16 years, 2 months ago (June 8, 2009)
Published Online	16 years, 2 months ago (June 11, 2009)
Published Print	16 years, 2 months ago (June 8, 2009)

Funders 0

None

BibTeX

@article{Wang_2009, title={Crystal and electronic structure of lithiated nanosized rutile TiO2 by electron diffraction and electron energy-loss spectroscopy}, volume={94}, ISSN={1077-3118}, url={http://dx.doi.org/10.1063/1.3152783}, DOI={10.1063/1.3152783}, number={23}, journal={Applied Physics Letters}, publisher={AIP Publishing}, author={Wang, C. M. and Yang, Z. G. and Thevuthasan, S. and Liu, J. and Baer, D. R. and Choi, D. and Wang, D. H. and Zhang, J. G. and Saraf, L. V. and Nie, Z. M.}, year={2009}, month=jun }

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