Abstract
The influence of hydrogen gas anneals on the electrical properties of nominally undoped, oxygen-deficient SrTiO3−x single crystals was investigated. Titanium getter layers and vacuum anneals were used to obtain oxygen-deficient SrTiO3−x with a low electrical resistivity. These crystals showed an optical absorption peak at 2.92 eV and strong midinfrared absorption. Subsequent anneals at 800 °C in forming gas, which contained 10% hydrogen, returned the crystals into the insulating, transparent state. The mechanisms by which hydrogen anneals can compensate for the effects of oxygen vacancies in SrTiO3−x are discussed. The results show that forming gas anneals of stoichiometric SrTiO3 can lead to complex electrical conduction behavior.
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Dates
Type | When |
---|---|
Created | 17 years ago (Aug. 6, 2008, 6:25 p.m.) |
Deposited | 2 years, 2 months ago (July 2, 2023, 11:53 a.m.) |
Indexed | 4 weeks, 2 days ago (Aug. 6, 2025, 8:27 a.m.) |
Issued | 17 years, 1 month ago (Aug. 4, 2008) |
Published | 17 years, 1 month ago (Aug. 4, 2008) |
Published Online | 17 years, 1 month ago (Aug. 6, 2008) |
Published Print | 17 years, 1 month ago (Aug. 4, 2008) |
@article{Jalan_2008, title={Effects of hydrogen anneals on oxygen deficient SrTiO3−x single crystals}, volume={93}, ISSN={1077-3118}, url={http://dx.doi.org/10.1063/1.2969037}, DOI={10.1063/1.2969037}, number={5}, journal={Applied Physics Letters}, publisher={AIP Publishing}, author={Jalan, Bharat and Engel-Herbert, Roman and Mates, Thomas E. and Stemmer, Susanne}, year={2008}, month=aug }