Abstract
We report measurements of thermal conductivity κ on individual gallium nitride nanowires (GaN NWs) with diameters ranging from 97to181nm grown by thermal chemical vapor deposition. We observed unexpectedly small κ values, in the range of 13–19W∕mK at 300K, with very weak diameter dependence. We also observe unusual power law κ∼Tn behavior with n=1.8 at low temperature. Electron-energy-loss-spectroscopy measurements indicate Si and O concentrations in the ranges of 0.1–1 and 0.01–0.1at.%, respectively. Based on extensive numerical calculations, we conclude that both the unexpectedly low κ and the T1.8 dependence are caused by unusually large mass-difference scattering, primarily from Si impurities. Our analysis also suggests that mass-difference scattering rates are significantly enhanced by the reduced phonon group velocity in nanoscale systems. Planar defects running the length of the NW, previously characterized in detail, may also play a role in limiting the phonon mean free path.
References
47
Referenced
92
10.1103/PhysRevB.58.1544
/ Phys. Rev. B (1998)10.1063/1.1345515
/ J. Appl. Phys. (2001)10.1103/PhysRevB.68.113308
/ Phys. Rev. B (2003)10.1103/PhysRevB.47.16631
/ Phys. Rev. B (1993)10.1115/1.2035114
/ ASME Trans. J. Heat Transfer (2005)10.1134/1.1914879
/ JETP Lett. (2005)10.1088/0022-3727/36/23/024
/ J. Phys. D (2003)10.1103/PhysRevLett.84.2857
/ Phys. Rev. Lett. (2000)10.1115/1.1597619
/ ASME Trans. J. Heat Transfer (2003)10.1063/1.1616981
/ Appl. Phys. Lett. (2003)10.1021/nl0486259
/ Nano Lett. (2005)10.1063/1.2058217
/ Appl. Phys. Lett. (2005)10.1021/nl0706143
/ Nano Lett. (2007)10.1063/1.1619221
/ Appl. Phys. Lett. (2003)10.1063/1.1697622
/ Appl. Phys. Lett. (2004)10.1016/0022-3697(77)90112-3
/ J. Phys. Chem. Solids (1977)10.1016/S0038-1098(03)00629-X
/ Solid State Commun. (2003)10.1007/978-3-662-04156-7_2
/ The Blue Laser Diode: The Complete Story (2000)10.1002/1521-4095(200011)12:21<1571::AID-ADMA1571>3.0.CO;2-T
/ Adv. Mater. (Weinheim, Ger.) (2000)10.1109/5.469300
/ Proc. IEEE (1995)10.1021/nl015667d
/ Nano Lett. (2002)10.1038/nmat728
/ Nat. Mater. (2002)10.1063/1.2115087
/ Appl. Phys. Lett. (2005)10.1002/adfm.200500807
/ Adv. Funct. Mater. (2006)10.1007/s00339-006-3705-y
/ Appl. Phys. A: Mater. Sci. Process. (2006)10.1063/1.1829780
/ Appl. Phys. Lett. (2004)10.1021/nl0515697
/ Nano Lett. (2005)10.1103/PhysRev.113.1046
/ Phys. Rev. (1959){'volume-title': 'Thermal Conduction in Solids', 'year': '1976', 'key': '2023063017431531900_c29'}
/ Thermal Conduction in Solids (1976)10.1103/PhysRevB.56.9431
/ Phys. Rev. B (1997)10.1063/1.1709746
/ J. Appl. Phys. (1967)10.1103/PhysRevB.19.3133
/ Phys. Rev. B (1979){'first-page': '64', 'volume-title': 'Thermal Conductivity of Solids', 'year': '1975', 'key': '2023063017431531900_c33'}
/ Thermal Conductivity of Solids (1975){'key': '2023063017431531900_c34', 'first-page': '393', 'volume': '16', 'year': '1979', 'journal-title': 'Rev. Int. Hautes Temp. Refract.'}
/ Rev. Int. Hautes Temp. Refract. (1979){'edition': '2nd ed.', 'volume-title': 'Physics of Semiconductor Devices', 'year': '1981', 'key': '2023063017431531900_c35'}
/ Physics of Semiconductor Devices (1981)10.1002/adma.200501832
/ Adv. Mater. (Weinheim, Ger.) (2006)10.1063/1.1868876
/ J. Appl. Phys. (2005)10.1088/0268-1242/19/4/156
/ Semicond. Sci. Technol. (2004)10.1063/1.125567
/ Appl. Phys. Lett. (1999)10.1063/1.373467
/ J. Appl. Phys. (2000)10.1063/1.1738172
/ Appl. Phys. Lett. (2004)10.1063/1.1682673
/ J. Appl. Phys. (2004)10.1103/PhysRevB.55.9571
/ Phys. Rev. B (1997)10.1007/s11664-006-0102-4
/ J. Electron. Mater. (2006)10.1016/j.jcrysgro.2005.11.079
/ J. Cryst. Growth (2006)10.1063/1.1927691
/ J. Appl. Phys. (2005){'key': '2023063017431531900_c47'}
Dates
Type | When |
---|---|
Created | 17 years, 4 months ago (March 29, 2008, 3:54 a.m.) |
Deposited | 2 years, 1 month ago (June 30, 2023, 2:12 p.m.) |
Indexed | 3 weeks, 6 days ago (July 30, 2025, 6:51 a.m.) |
Issued | 17 years, 5 months ago (March 15, 2008) |
Published | 17 years, 5 months ago (March 15, 2008) |
Published Online | 17 years, 4 months ago (March 28, 2008) |
Published Print | 17 years, 5 months ago (March 15, 2008) |
@article{Guthy_2008, title={Unusually low thermal conductivity of gallium nitride nanowires}, volume={103}, ISSN={1089-7550}, url={http://dx.doi.org/10.1063/1.2894907}, DOI={10.1063/1.2894907}, number={6}, journal={Journal of Applied Physics}, publisher={AIP Publishing}, author={Guthy, Csaba and Nam, Chang-Yong and Fischer, John E.}, year={2008}, month=mar }