DOI: 10.1063/1.2819606. Epitaxial stabilization and structural properties of REMnO3 (RE=Dy,Gd,Sm) compounds in a layered, hexagonal ABO3 structure

Epitaxial stabilization and structural properties of REMnO3 (RE=Dy,Gd,Sm) compounds in a layered, hexagonal ABO3 structure

10.1063/1.2819606

Crossref journal-article

AIP Publishing

Applied Physics Letters (317)

Abstract

RE Mn O 3 (RE=Dy,Gd,Sm) films were deposited on (110) surfaces of single crystalline hexagonal (h-)YMnO3. These films adopted the metastable multiferroic h-REMnO3 structure instead of the stable perovskite structure. Sharp (hh0) diffraction peaks with narrow rocking curves were found for all films. The peak widths increased with increasing size of the rare-earth cation. The c-axis/a-axis lattice parameter decreased/increased monotonically with increasing rare-earth size for these epitaxial films. All films exhibited the following epitaxial relationship {110}REMnO3‖{110}YMnO3;⟨11¯0⟩REMnO3‖⟨11¯0⟩YMnO3. The single-phase hexagonal films were kinetically robust against back transformation to the stable perovskite structure even to thicknesses of 50nm.

Bibliography

Balasubramaniam, K. R., Havelia, S., Salvador, P. A., Zheng, H., & Mitchell, J. F. (2007). Epitaxial stabilization and structural properties of REMnO3â(RE=Dy,Gd,Sm) compounds in a layered, hexagonal ABO3 structure. Applied Physics Letters, 91(23).

Authors 5

K. R. Balasubramaniam (first)
S. Havelia (additional)
P. A. Salvador (additional)
H. Zheng (additional)
J. F. Mitchell (additional)

References 19 Referenced 29

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10.1038/nmat1080 / Nat. Mater. (2004)
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Dates

Type	When
Created	17 years, 8 months ago (Dec. 3, 2007, 7:08 p.m.)
Deposited	2 years, 1 month ago (July 2, 2023, 11:31 a.m.)
Indexed	3 weeks, 1 day ago (July 30, 2025, 6:49 a.m.)
Issued	17 years, 8 months ago (Dec. 3, 2007)
Published	17 years, 8 months ago (Dec. 3, 2007)
Published Online	17 years, 8 months ago (Dec. 3, 2007)
Published Print	17 years, 8 months ago (Dec. 3, 2007)

Funders 0

None

BibTeX

@article{Balasubramaniam_2007, title={Epitaxial stabilization and structural properties of REMnO3 (RE=Dy,Gd,Sm) compounds in a layered, hexagonal ABO3 structure}, volume={91}, ISSN={1077-3118}, url={http://dx.doi.org/10.1063/1.2819606}, DOI={10.1063/1.2819606}, number={23}, journal={Applied Physics Letters}, publisher={AIP Publishing}, author={Balasubramaniam, K. R. and Havelia, S. and Salvador, P. A. and Zheng, H. and Mitchell, J. F.}, year={2007}, month=dec }

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