DOI: 10.1063/1.2803745. Crystal structure and thermoelectric properties of type-III clathrate compounds in the Ba–In

Crystal structure and thermoelectric properties of type-III clathrate compounds in the Ba–In–Ge system

10.1063/1.2803745

Crossref journal-article

AIP Publishing

Journal of Applied Physics (317)

Abstract

The crystal structure and thermoelectric properties of type-III clathrate compounds in the Ba–In–Ge system have been investigated as a function of In content. The solid solubility of In in the type-III clathrate compounds is determined to be about X=15 when expressed with the formula of Ba24InXGe100−X. Similar to our recent results obtained for type-III clathrate compounds in Ba–Al–Ge and Ba–Ga–Ge systems, values of electrical resistivity, Seebeck coefficient, and electronic thermal conductivity of those in the Ba–In–Ge system generally increase with the increase in the In content because of the decrease in the number of excess electrons as described with the simple Zintl concept. The changes in their lattice thermal conductivity with the In content are explained in terms not only of the low rattling frequency of the guest atom but also of the low Debye temperature of the cage framework.

Bibliography

Kim, J.-H., Okamoto, N. L., Kishida, K., Tanaka, K., & Inui, H. (2007). Crystal structure and thermoelectric properties of type-III clathrate compounds in the BaâInâGe system. Journal of Applied Physics, 102(9).

Authors 5

Jung-Hwan Kim (first)
Norihiko L. Okamoto (additional)
Kyosuke Kishida (additional)
Katsushi Tanaka (additional)
Haruyuki Inui (additional)

References 23 Referenced 17

{'key': '2023080703491654600_c1', 'first-page': '407', 'volume-title': 'CRC Handbook of Thermoelectrics', 'author': 'Rowe', 'year': '1995'} / CRC Handbook of Thermoelectrics by Rowe (1995)
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{'first-page': '191', 'volume-title': 'Thermoelectrics: Basic Principles and New Materials Developments', 'year': '2001', 'key': '2023080703491654600_c4'} / Thermoelectrics: Basic Principles and New Materials Developments (2001)
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{'volume-title': 'International Tables for Crystallography. Space-Group Symmetry', 'year': '1996', 'key': '2023080703491654600_c7'} / International Tables for Crystallography. Space-Group Symmetry (1996)
10.1103/PhysRevB.65.134435 / Phys. Rev. B (2002)
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{'key': '2023080703491654600_c11', 'first-page': '207', 'volume': '215', 'year': '2000', 'journal-title': 'Z. Kristallogr.'} / Z. Kristallogr. (2000)
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Dates

Type	When
Created	17 years, 9 months ago (Nov. 6, 2007, 6:09 p.m.)
Deposited	2 years ago (Aug. 6, 2023, 11:49 p.m.)
Indexed	1 month ago (July 30, 2025, 6:50 a.m.)
Issued	17 years, 10 months ago (Nov. 1, 2007)
Published	17 years, 10 months ago (Nov. 1, 2007)
Published Online	17 years, 9 months ago (Nov. 6, 2007)
Published Print	17 years, 10 months ago (Nov. 1, 2007)

Funders 0

None

BibTeX

@article{Kim_2007, title={Crystal structure and thermoelectric properties of type-III clathrate compounds in the Ba–In–Ge system}, volume={102}, ISSN={1089-7550}, url={http://dx.doi.org/10.1063/1.2803745}, DOI={10.1063/1.2803745}, number={9}, journal={Journal of Applied Physics}, publisher={AIP Publishing}, author={Kim, Jung-Hwan and Okamoto, Norihiko L. and Kishida, Kyosuke and Tanaka, Katsushi and Inui, Haruyuki}, year={2007}, month=nov }

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