DOI: 10.1063/1.2738471. The laboratory glass transition

10.1063/1.2738471

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The phenomenology of the laboratory glass transition is examined in the enthalpy landscape framework. It is shown that a generic description of the glassy state based on partitioning of the phase space caused by the finiteness of the time of observation explains all universal features of glass transition. Using this description of glass, which is referred to as the extrinsically constrained liquid, expressions are derived for properties of glass and for property changes at the laboratory glass transition. A model enthalpy landscape is used to illustrate the basic concepts of this description. Additional new consequences of this description, such as the role of complexity in glass transition and the zero residual entropy of a glass, are discussed.

Bibliography

Gupta, P. K., & Mauro, J. C. (2007). The laboratory glass transition. The Journal of Chemical Physics, 126(22).

Authors 2

Prabhat K. Gupta (first)
John C. Mauro (additional)

References 49 Referenced 105

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Dates

Type	When
Created	18 years, 2 months ago (June 11, 2007, 10:26 p.m.)
Deposited	2 years, 2 months ago (June 26, 2023, 10:01 a.m.)
Indexed	3 weeks, 3 days ago (Aug. 6, 2025, 9:04 a.m.)
Issued	18 years, 2 months ago (June 11, 2007)
Published	18 years, 2 months ago (June 11, 2007)
Published Online	18 years, 2 months ago (June 11, 2007)
Published Print	18 years, 2 months ago (June 14, 2007)

Funders 0

None

BibTeX

@article{Gupta_2007, title={The laboratory glass transition}, volume={126}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.2738471}, DOI={10.1063/1.2738471}, number={22}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Gupta, Prabhat K. and Mauro, John C.}, year={2007}, month=jun }

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      ]
    ]
  },
  "references-count": 49,
  "journal-issue": {
    "issue": "22",
    "published-print": {
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        [
          2007,
          6,
          14
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.2738471",
  "relation": {},
  "ISSN": [
    "0021-9606",
    "1089-7690"
  ],
  "subject": [],
  "published-other": {
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        2007,
        6,
        14
      ]
    ]
  },
  "published": {
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        6,
        11
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  "article-number": "224504"
}