DOI: 10.1063/1.2721554. Spontaneous and induced dynamic fluctuations in glass formers. I. General results and dependence on ensemble and dynamics

Spontaneous and induced dynamic fluctuations in glass formers. I. General results and dependence on ensemble and dynamics

10.1063/1.2721554

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

We study theoretically and numerically a family of multipoint dynamic susceptibilities that quantify the strength and characteristic length scales of dynamic heterogeneities in glass-forming materials. We use general theoretical arguments (fluctuation-dissipation relations and symmetries of relevant dynamical field theories) to relate the sensitivity of averaged two-time correlators to temperature and density to spontaneous fluctuations of the local dynamics. Our theoretical results are then compared to molecular dynamics simulations of the Newtonian, Brownian, and Monte Carlo dynamics of two representative glass-forming liquids, a fragile binary Lennard-Jones mixture, and a model for the strong glass-former silica. We justify in detail the claim made by Berthier et al. [Science 310, 1797 (2005)] that the temperature dependence of correlation functions allows one to extract useful information on dynamic length scales in glassy systems. We also discuss some subtle issues associated with the choice of microscopic dynamics and of statistical ensemble through conserved quantities, which are found to play an important role in determining dynamic correlations.

Bibliography

Berthier, L., Biroli, G., Bouchaud, J.-P., Kob, W., Miyazaki, K., & Reichman, D. R. (2007). Spontaneous and induced dynamic fluctuations in glass formers. I. General results and dependence on ensemble and dynamics. The Journal of Chemical Physics, 126(18).

Authors 6

L. Berthier (first)
G. Biroli (additional)
J.-P. Bouchaud (additional)
W. Kob (additional)
K. Miyazaki (additional)
D. R. Reichman (additional)

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Dates

Type	When
Created	18 years, 3 months ago (May 8, 2007, 6:31 p.m.)
Deposited	2 years, 1 month ago (June 30, 2023, 4:18 p.m.)
Indexed	3 weeks ago (Aug. 6, 2025, 9:04 a.m.)
Issued	18 years, 3 months ago (May 8, 2007)
Published	18 years, 3 months ago (May 8, 2007)
Published Online	18 years, 3 months ago (May 8, 2007)
Published Print	18 years, 3 months ago (May 14, 2007)

Funders 0

None

BibTeX

@article{Berthier_2007, title={Spontaneous and induced dynamic fluctuations in glass formers. I. General results and dependence on ensemble and dynamics}, volume={126}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.2721554}, DOI={10.1063/1.2721554}, number={18}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Berthier, L. and Biroli, G. and Bouchaud, J.-P. and Kob, W. and Miyazaki, K. and Reichman, D. R.}, year={2007}, month=may }

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