DOI: 10.1063/1.2400038. Liquid-liquid transition in supercooled water investigated by interaction with LiCl and Xe

Liquid-liquid transition in supercooled water investigated by interaction with LiCl and Xe

10.1063/1.2400038

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The hypothesis that supercooled water consists of two distinct liquid phases has been explored on the basis of their ability to hydrate nonpolar (Xe) and electrolytic (LiCl) species. Xe incorporated in the bulk of amorphous solid water survives in the deeply supercooled regime above the glass-transition temperature of 136K and is finally dehydrated at 165K, whereas LiCl dissolves only in the liquid phase appearing above 165K. The second liquid phase connects with normal water as inferred from high (poor) solubility of LiCl(Xe). This result also suggests that decoupling of translational diffusion and viscosity in the deeply supercooled regime is caused by domain structures of the two liquid phases formed during a possible liquid-liquid transition.

Bibliography

Souda, R. (2006). Liquid-liquid transition in supercooled water investigated by interaction with LiCl and Xe. The Journal of Chemical Physics, 125(18).

Authors 1

Ryutaro Souda (first)

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Dates

Type	When
Created	18 years, 9 months ago (Nov. 15, 2006, 5:16 p.m.)
Deposited	2 years, 2 months ago (June 26, 2023, 12:01 a.m.)
Indexed	4 weeks ago (July 30, 2025, 6:48 a.m.)
Issued	18 years, 9 months ago (Nov. 14, 2006)
Published	18 years, 9 months ago (Nov. 14, 2006)
Published Online	18 years, 9 months ago (Nov. 14, 2006)
Published Print	18 years, 9 months ago (Nov. 14, 2006)

Funders 0

None

BibTeX

@article{Souda_2006, title={Liquid-liquid transition in supercooled water investigated by interaction with LiCl and Xe}, volume={125}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.2400038}, DOI={10.1063/1.2400038}, number={18}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Souda, Ryutaro}, year={2006}, month=nov }

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