DOI: 10.1063/1.2208298. Raman spectroscopy of (Mn, Co)-codoped ZnO films

Raman spectroscopy of (Mn, Co)-codoped ZnO films

10.1063/1.2208298

Crossref journal-article

AIP Publishing

Journal of Applied Physics (317)

Abstract

Raman spectra of (Mn, Co)-codoped ZnO films were investigated as functions of laser line and temperature. It is shown that the Raman shifts for different phonon modes exhibit redshift with temperature increasing, which can be attributed to the anharmonic effect in the material. Strong resonant Raman spectra of multi-LO phonons were observed as well for the films with the exciting photon energy higher than the direct band gap. Compared with the Raman spectra for ZnO films, the Mn, Co codoping effect on the spectra is revealed by the presence of additional phonon modes at 275 and 642cm−1 and another intensive phonon mode at around 524cm−1. With postannealing, Raman intensity of these phonon modes decrease, owing to the incorporation of oxygen into the films. Origins of the different phonon modes in the spectra are discussed as well.

Bibliography

Du, C. L., Gu, Z. B., Lu, M. H., Wang, J., Zhang, S. T., Zhao, J., Cheng, G. X., Heng, H., & Chen, Y. F. (2006). Raman spectroscopy of (Mn, Co)-codoped ZnO films. Journal of Applied Physics, 99(12).

Authors 9

C. L. Du (first)
Z. B. Gu (additional)
M. H. Lu (additional)
J. Wang (additional)
S. T. Zhang (additional)
J. Zhao (additional)
G. X. Cheng (additional)
H. Heng (additional)
Y. F. Chen (additional)

References 31 Referenced 137

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Dates

Type	When
Created	19 years ago (Aug. 9, 2006, 1:02 p.m.)
Deposited	2 years ago (Aug. 4, 2023, 5:03 p.m.)
Indexed	3 days, 16 hours ago (Aug. 19, 2025, 6:54 a.m.)
Issued	19 years, 2 months ago (June 15, 2006)
Published	19 years, 2 months ago (June 15, 2006)
Published Online	19 years, 1 month ago (June 26, 2006)
Published Print	19 years, 2 months ago (June 15, 2006)

Funders 0

None

BibTeX

@article{Du_2006, title={Raman spectroscopy of (Mn, Co)-codoped ZnO films}, volume={99}, ISSN={1089-7550}, url={http://dx.doi.org/10.1063/1.2208298}, DOI={10.1063/1.2208298}, number={12}, journal={Journal of Applied Physics}, publisher={AIP Publishing}, author={Du, C. L. and Gu, Z. B. and Lu, M. H. and Wang, J. and Zhang, S. T. and Zhao, J. and Cheng, G. X. and Heng, H. and Chen, Y. F.}, year={2006}, month=jun }

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  "abstract": "<jats:p>Raman spectra of (Mn, Co)-codoped ZnO films were investigated as functions of laser line and temperature. It is shown that the Raman shifts for different phonon modes exhibit redshift with temperature increasing, which can be attributed to the anharmonic effect in the material. Strong resonant Raman spectra of multi-LO phonons were observed as well for the films with the exciting photon energy higher than the direct band gap. Compared with the Raman spectra for ZnO films, the Mn, Co codoping effect on the spectra is revealed by the presence of additional phonon modes at 275 and 642cm\u22121 and another intensive phonon mode at around 524cm\u22121. With postannealing, Raman intensity of these phonon modes decrease, owing to the incorporation of oxygen into the films. Origins of the different phonon modes in the spectra are discussed as well.</jats:p>",
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