Abstract
A white light polymer light-emitting diode was demonstrated with a double layer configuration: poly[N,N′-bis(4-butylphenyl)-N,N′-bis(phenyl)benzidine] (poly-TPD) blended with poly(N-vinylcarbazole) as both hole-transporting layer and electron-blocking layer, blue-emissive poly(9,9-dihexylfluorene-alt-co-2,5-dioctyloxy-para-phenylene) (PDHFDOOP) blended with green-emissive poly[6,6′-bi-(9,9′-dihexylfluorene)-co-(9,9′-dihexylfluorene-3-thiophene-5′-yl)] as an emissive layer. By annealing the emissive layer at a relatively high temperature, fluorenone defects were generated into PDHFDOOP, which formed an exciplex with poly-TPD, as a red emitter. The devices exhibit a maximum brightness of ∼4800cd∕m2 and a maximum luminous efficiency of ∼3cd∕A. Moreover, the Commission Internationale de L’Eclairage coordinates of the emitted light is close to that of pure white light and is insensitive to the applied voltages.
References
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Dates
Type | When |
---|---|
Created | 19 years, 4 months ago (April 18, 2006, 6:16 p.m.) |
Deposited | 2 years, 2 months ago (June 25, 2023, 1:35 p.m.) |
Indexed | 1 month ago (July 30, 2025, 6:47 a.m.) |
Issued | 19 years, 4 months ago (April 17, 2006) |
Published | 19 years, 4 months ago (April 17, 2006) |
Published Online | 19 years, 4 months ago (April 19, 2006) |
Published Print | 19 years, 4 months ago (April 17, 2006) |
@article{Sun_2006, title={White light from polymer light-emitting diodes: Utilization of fluorenone defects and exciplex}, volume={88}, ISSN={1077-3118}, url={http://dx.doi.org/10.1063/1.2197318}, DOI={10.1063/1.2197318}, number={16}, journal={Applied Physics Letters}, publisher={AIP Publishing}, author={Sun, Q. J. and Fan, B. H. and Tan, Z. A. and Yang, C. H. and Li, Y. F. and Yang, Y.}, year={2006}, month=apr }