DOI: 10.1063/1.2193159. The fragile-to-strong dynamic crossover transition in confined water: nuclear magnetic resonance results

The fragile-to-strong dynamic crossover transition in confined water: nuclear magnetic resonance results

10.1063/1.2193159

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

By means of a nuclear magnetic resonance experiment, we give evidence of the existence of a fragile-to-strong dynamic crossover transition (FST) in confined water at a temperature TL=223±2K. We have studied the dynamics of water contained in 1D cylindrical nanoporous matrices (MCM-41-S) in the temperature range 190–280K, where experiments on bulk water were so far hampered by crystallization. The FST is clearly inferred from the T dependence of the inverse of the self-diffusion coefficient of water (1∕D) as a crossover point from a non-Arrhenius to an Arrhenius behavior. The combination of the measured self-diffusion coefficient D and the average translational relaxation time ⟨τT⟩, as measured by neutron scattering, shows the predicted breakdown of Stokes-Einstein relation in deeply supercooled water.

Bibliography

Mallamace, F., Broccio, M., Corsaro, C., Faraone, A., Wanderlingh, U., Liu, L., Mou, C.-Y., & Chen, S. H. (2006). The fragile-to-strong dynamic crossover transition in confined water: nuclear magnetic resonance results. The Journal of Chemical Physics, 124(16).

Authors 8

F. Mallamace (first)
M. Broccio (additional)
C. Corsaro (additional)
A. Faraone (additional)
U. Wanderlingh (additional)
L. Liu (additional)
C.-Y. Mou (additional)
S. H. Chen (additional)

References 27 Referenced 181

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Dates

Type	When
Created	19 years, 4 months ago (April 25, 2006, 6:16 p.m.)
Deposited	2 years, 1 month ago (June 30, 2023, 1:47 p.m.)
Indexed	3 weeks, 6 days ago (July 30, 2025, 11:21 a.m.)
Issued	19 years, 4 months ago (April 27, 2006)
Published	19 years, 4 months ago (April 27, 2006)
Published Online	19 years, 4 months ago (April 27, 2006)
Published Print	19 years, 3 months ago (April 28, 2006)

Funders 0

None

BibTeX

@article{Mallamace_2006, title={The fragile-to-strong dynamic crossover transition in confined water: nuclear magnetic resonance results}, volume={124}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.2193159}, DOI={10.1063/1.2193159}, number={16}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Mallamace, F. and Broccio, M. and Corsaro, C. and Faraone, A. and Wanderlingh, U. and Liu, L. and Mou, C.-Y. and Chen, S. H.}, year={2006}, month=apr }

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