DOI: 10.1063/1.2190273. Fast synthesis method and phase diagram of hydrogen clathrate hydrate

Fast synthesis method and phase diagram of hydrogen clathrate hydrate

10.1063/1.2190273

Crossref journal-article

AIP Publishing

Applied Physics Letters (317)

Abstract

We report a very fast method for hydrogen clathrate production. The formation of hydrogen clathrate from H2 gas and ice-Ih at 77–273K occurs at least 100 times faster compared to the reaction with water. This effect is probably the result of a partial penetration of hydrogen into the ice-Ih body, which favors clathrate formation. With the ice method, the ice-Ih∕48H2*136H2O system can quickly trap and release up to 3.77 mass % of hydrogen, which gives it an advantage over other chemical-bonding hydrogen storage technologies. New data on the hydrogen-water phase diagram are presented and discussed.

Bibliography

Lokshin, K. A., & Zhao, Y. (2006). Fast synthesis method and phase diagram of hydrogen clathrate hydrate. Applied Physics Letters, 88(13).

Authors 2

Konstantin A. Lokshin (first)
Yusheng Zhao (additional)

References 16 Referenced 88

{'edition': '2nd ed', 'volume-title': 'Clathrate Hydrates of Natural Gases', 'year': '1998', 'key': '2023070301270880300_c1'} / Clathrate Hydrates of Natural Gases (1998)
10.1038/35070513 / Nature (London) (2001)
10.1016/0019-1035(87)90075-3 / Icarus (1987)
10.1029/98JD00686 / J. Geophys. Res. (1998)
10.1070/mc1999v009n05ABEH001104 / Mendeleev Commun. (1999)
10.1007/BF02903454 / J. Struct. Chem. (1999)
10.1073/pnas.0307449100 / Proc. Natl. Acad. Sci. U.S.A. (2004)
{'key': '2023070301270880300_c8'}
10.1126/science.1075394 / Science (2002)
10.1103/PhysRevLett.93.125503 / Phys. Rev. Lett. (2004)
10.1126/science.1102076 / Science (2004)
10.1038/nature03457 / Nature (London) (2005)
10.1063/1.1928448 / Rev. Sci. Instrum. (2005)
10.1103/PhysRevLett.71.3150 / Phys. Rev. Lett. (1993)
10.2138/am-1995-11-1220 / Am. Mineral. (1995)
10.1038/332141a0 / Nature (London) (1988)

Dates

Type	When
Created	19 years, 4 months ago (March 28, 2006, 6:15 p.m.)
Deposited	2 years, 1 month ago (July 2, 2023, 9:27 p.m.)
Indexed	6 days, 3 hours ago (Aug. 21, 2025, 2:03 p.m.)
Issued	19 years, 5 months ago (March 27, 2006)
Published	19 years, 5 months ago (March 27, 2006)
Published Online	19 years, 4 months ago (March 29, 2006)
Published Print	19 years, 5 months ago (March 27, 2006)

Funders 0

None

BibTeX

@article{Lokshin_2006, title={Fast synthesis method and phase diagram of hydrogen clathrate hydrate}, volume={88}, ISSN={1077-3118}, url={http://dx.doi.org/10.1063/1.2190273}, DOI={10.1063/1.2190273}, number={13}, journal={Applied Physics Letters}, publisher={AIP Publishing}, author={Lokshin, Konstantin A. and Zhao, Yusheng}, year={2006}, month=mar }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        8,
        21
      ]
    ],
    "date-time": "2025-08-21T18:03:23Z",
    "timestamp": 1755799403934,
    "version": "3.41.2"
  },
  "reference-count": 16,
  "publisher": "AIP Publishing",
  "issue": "13",
  "content-domain": {
    "domain": [
      "pubs.aip.org"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        2006,
        3,
        27
      ]
    ]
  },
  "abstract": "<jats:p>We report a very fast method for hydrogen clathrate production. The formation of hydrogen clathrate from H2 gas and ice-Ih at 77\u2013273K occurs at least 100 times faster compared to the reaction with water. This effect is probably the result of a partial penetration of hydrogen into the ice-Ih body, which favors clathrate formation. With the ice method, the ice-Ih\u221548H2*136H2O system can quickly trap and release up to 3.77 mass % of hydrogen, which gives it an advantage over other chemical-bonding hydrogen storage technologies. New data on the hydrogen-water phase diagram are presented and discussed.</jats:p>",
  "DOI": "10.1063/1.2190273",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2006,
        3,
        28
      ]
    ],
    "date-time": "2006-03-28T23:15:02Z",
    "timestamp": 1143587702000
  },
  "update-policy": "https://doi.org/10.1063/aip-crossmark-policy-page",
  "source": "Crossref",
  "is-referenced-by-count": 88,
  "title": "Fast synthesis method and phase diagram of hydrogen clathrate hydrate",
  "prefix": "10.1063",
  "volume": "88",
  "author": [
    {
      "given": "Konstantin A.",
      "family": "Lokshin",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Los Alamos National Laboratory LANSCE-12, , Los Alamos, New Mexico 87544"
        }
      ]
    },
    {
      "given": "Yusheng",
      "family": "Zhao",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Los Alamos National Laboratory LANSCE-12, , Los Alamos, New Mexico 87544"
        }
      ]
    }
  ],
  "member": "317",
  "published-online": {
    "date-parts": [
      [
        2006,
        3,
        29
      ]
    ]
  },
  "reference": [
    {
      "edition": "2nd ed",
      "volume-title": "Clathrate Hydrates of Natural Gases",
      "year": "1998",
      "key": "2023070301270880300_c1"
    },
    {
      "key": "2023070301270880300_c2",
      "doi-asserted-by": "publisher",
      "first-page": "661",
      "DOI": "10.1038/35070513",
      "volume": "410",
      "year": "2001",
      "journal-title": "Nature (London)"
    },
    {
      "key": "2023070301270880300_c3",
      "doi-asserted-by": "publisher",
      "first-page": "61",
      "DOI": "10.1016/0019-1035(87)90075-3",
      "volume": "70",
      "year": "1987",
      "journal-title": "Icarus"
    },
    {
      "key": "2023070301270880300_c4",
      "doi-asserted-by": "publisher",
      "first-page": "15971",
      "DOI": "10.1029/98JD00686",
      "volume": "103",
      "year": "1998",
      "journal-title": "J. Geophys. Res."
    },
    {
      "key": "2023070301270880300_c5",
      "doi-asserted-by": "publisher",
      "first-page": "209",
      "DOI": "10.1070/mc1999v009n05ABEH001104",
      "volume": "5",
      "year": "1999",
      "journal-title": "Mendeleev Commun."
    },
    {
      "key": "2023070301270880300_c6",
      "doi-asserted-by": "crossref",
      "first-page": "790",
      "DOI": "10.1007/BF02903454",
      "volume": "40",
      "year": "1999",
      "journal-title": "J. Struct. Chem."
    },
    {
      "key": "2023070301270880300_c7",
      "doi-asserted-by": "publisher",
      "first-page": "708",
      "DOI": "10.1073/pnas.0307449100",
      "volume": "101",
      "year": "2004",
      "journal-title": "Proc. Natl. Acad. Sci. U.S.A."
    },
    {
      "key": "2023070301270880300_c8"
    },
    {
      "key": "2023070301270880300_c9",
      "doi-asserted-by": "publisher",
      "first-page": "2247",
      "DOI": "10.1126/science.1075394",
      "volume": "297",
      "year": "2002",
      "journal-title": "Science"
    },
    {
      "key": "2023070301270880300_c10",
      "doi-asserted-by": "publisher",
      "first-page": "125503",
      "DOI": "10.1103/PhysRevLett.93.125503",
      "volume": "93",
      "year": "2004",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "2023070301270880300_c11",
      "doi-asserted-by": "publisher",
      "first-page": "469",
      "DOI": "10.1126/science.1102076",
      "volume": "306",
      "year": "2004",
      "journal-title": "Science"
    },
    {
      "key": "2023070301270880300_c12",
      "doi-asserted-by": "publisher",
      "first-page": "743",
      "DOI": "10.1038/nature03457",
      "volume": "434",
      "year": "2005",
      "journal-title": "Nature (London)"
    },
    {
      "key": "2023070301270880300_c13",
      "doi-asserted-by": "publisher",
      "first-page": "063909",
      "DOI": "10.1063/1.1928448",
      "volume": "76",
      "year": "2005",
      "journal-title": "Rev. Sci. Instrum."
    },
    {
      "key": "2023070301270880300_c14",
      "doi-asserted-by": "publisher",
      "first-page": "3150",
      "DOI": "10.1103/PhysRevLett.71.3150",
      "volume": "71",
      "year": "1993",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "2023070301270880300_c15",
      "doi-asserted-by": "crossref",
      "first-page": "1302",
      "DOI": "10.2138/am-1995-11-1220",
      "volume": "80",
      "year": "1995",
      "journal-title": "Am. Mineral."
    },
    {
      "key": "2023070301270880300_c16",
      "doi-asserted-by": "publisher",
      "first-page": "141",
      "DOI": "10.1038/332141a0",
      "volume": "332",
      "year": "1988",
      "journal-title": "Nature (London)"
    }
  ],
  "container-title": "Applied Physics Letters",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.aip.org/aip/apl/article-pdf/doi/10.1063/1.2190273/14009225/131909_1_online.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://pubs.aip.org/aip/apl/article-pdf/doi/10.1063/1.2190273/14009225/131909_1_online.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2023,
        7,
        3
      ]
    ],
    "date-time": "2023-07-03T01:27:12Z",
    "timestamp": 1688347632000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.aip.org/apl/article/88/13/131909/330893/Fast-synthesis-method-and-phase-diagram-of"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        2006,
        3,
        27
      ]
    ]
  },
  "references-count": 16,
  "journal-issue": {
    "issue": "13",
    "published-print": {
      "date-parts": [
        [
          2006,
          3,
          27
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.2190273",
  "relation": {},
  "ISSN": [
    "0003-6951",
    "1077-3118"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        2006,
        3,
        27
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        2006,
        3,
        27
      ]
    ]
  },
  "article-number": "131909"
}