DOI: 10.1063/1.2149852. Recombination of photodissociated iodine: A time-resolved x-ray-diffraction study

Recombination of photodissociated iodine: A time-resolved x-ray-diffraction study

10.1063/1.2149852

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

A time-resolved x-ray-diffraction experiment is presented that aims to study the recombination of laser-dissociated iodine molecules dissolved in CCl4. This process is monitored over an extended time interval from pico- to microseconds. The variations of atom-atom distances are probed with a milliangstrom resolution. A recent theory of time-resolved x-ray diffraction is used to analyze the experimental data; it employs the correlation function approach of statistical mechanics. The most striking outcome of this study is the experimental determination of time-dependent I–I atom-atom distribution functions. The structure of the CCl4 solvent changes simultaneously; the solvent thus appears as a reaction partner rather than an inert medium hosting it. Thermal expansion of the system is nonuniform in time, an effect due to the presence of the acoustic horizon. One concludes that a time-resolved x-ray diffraction permits real-time visualization of solvent and solute motions during a chemical reaction.

Bibliography

Wulff, M., Bratos, S., Plech, A., Vuilleumier, R., Mirloup, F., Lorenc, M., Kong, Q., & Ihee, H. (2006). Recombination of photodissociated iodine: A time-resolved x-ray-diffraction study. The Journal of Chemical Physics, 124(3).

Authors 8

M. Wulff (first)
S. Bratos (additional)
A. Plech (additional)
R. Vuilleumier (additional)
F. Mirloup (additional)
M. Lorenc (additional)
Q. Kong (additional)
H. Ihee (additional)

References 39 Referenced 55

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Dates

Type	When
Created	19 years, 7 months ago (Jan. 12, 2006, 6:05 p.m.)
Deposited	2 years, 1 month ago (July 15, 2023, 1:09 a.m.)
Indexed	3 weeks, 5 days ago (July 30, 2025, 6:46 a.m.)
Issued	19 years, 7 months ago (Jan. 17, 2006)
Published	19 years, 7 months ago (Jan. 17, 2006)
Published Online	19 years, 7 months ago (Jan. 17, 2006)
Published Print	19 years, 7 months ago (Jan. 21, 2006)

Funders 0

None

BibTeX

@article{Wulff_2006, title={Recombination of photodissociated iodine: A time-resolved x-ray-diffraction study}, volume={124}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.2149852}, DOI={10.1063/1.2149852}, number={3}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Wulff, M. and Bratos, S. and Plech, A. and Vuilleumier, R. and Mirloup, F. and Lorenc, M. and Kong, Q. and Ihee, H.}, year={2006}, month=jan }

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