Crossref journal-article
AIP Publishing
Journal of Applied Physics (317)
Abstract

We demonstrate ambipolar charge transport in organic field-effect transistors based on the solution processible methanofullerene [6,6]-phenyl-C71-butyric acid methyl ester ([70]PCBM). The electron mobility measured in the linear and saturated regimes is approximately equal and of the order of 1×10−3cm2∕Vs. In the linear regime, mobility is thermally activated with a strong gate bias dependence. The p-channel hole mobility is lower with a maximum value of 2×10−5cm2∕Vs. The n- and p-channel operations are characterized by a low (∼∣3∣V) and a high (∼∣50∣V) switch-on voltage, respectively, with the on-off current ratio on the order of 104 for both channels. Although the present findings are qualitatively similar to those reported previously for C60-methanofullerene-based transistors, [70]PCBM devices are more stable and easier to reproduce. By making use of this property we are able to demonstrate functional unipolar and complementarylike logic circuits with promising operating characteristics.

Bibliography

Anthopoulos, T. D., de Leeuw, D. M., Cantatore, E., van ’t Hof, P., Alma, J., & Hummelen, J. C. (2005). Solution processible organic transistors and circuits based on a C70 methanofullerene. Journal of Applied Physics, 98(5).

Authors 6
  1. Thomas D. Anthopoulos (first)
  2. Dago M. de Leeuw (additional)
  3. Eugenio Cantatore (additional)
  4. Patrick van ’t Hof (additional)
  5. Jan Alma (additional)
  6. Jan C. Hummelen (additional)
References 40 Referenced 97
  1. 10.1063/1.1290728 / Appl. Phys. Lett. (2000)
  2. 10.1038/35035212 / Nature (London) (2000)
  3. 10.1038/414599a / Nature (London) (2001)
  4. 10.1002/1521-4095(20020116)14:2<99::AID-ADMA99>3.0.CO;2-9 / Adv. Mater. (Weinheim, Ger.) (2002)
  5. 10.1038/nmat1061 / Nat. Mater. (2004)
  6. {'key': '2023063017172096000_c6', 'first-page': '293'}
  7. 10.1126/science.270.5238.972 / Science (1995)
  8. 10.1021/ja9727629 / J. Am. Chem. Soc. (1998)
  9. 10.1126/science.280.5370.1741 / Science (1998)
  10. 10.1016/S0379-6779(97)80881-8 / Synth. Met. (1997)
  11. 10.1038/35000530 / Nature (London) (2000)
  12. 10.1126/science.1094196 / Science (2004)
  13. 10.1038/35006603 / Nature (London) (2000)
  14. 10.1063/1.115503 / Appl. Phys. Lett. (1995)
  15. 10.1021/ja953881w / J. Am. Chem. Soc. (1996)
  16. 10.1063/1.1667013 / Appl. Phys. Lett. (2004)
  17. 10.1016/j.cplett.2003.07.025 / Chem. Phys. Lett. (2003)
  18. 10.1021/ja034944a / J. Am. Chem. Soc. (2003)
  19. 10.1063/1.1695193 / Appl. Phys. Lett. (2004)
  20. 10.1063/1.1577383 / Appl. Phys. Lett. (2003)
  21. 10.1063/1.1505746 / Appl. Phys. Lett. (2002)
  22. 10.1002/adma.200305623 / Adv. Mater. (Weinheim, Ger.) (2003)
  23. 10.1002/adma.200400309 / Adv. Mater. (Weinheim, Ger.) (2004)
  24. 10.1063/1.1895466 / J. Appl. Phys. (2005)
  25. 10.1063/1.1812577 / Appl. Phys. Lett. (2004)
  26. 10.1021/jo00108a012 / J. Org. Chem. (1995)
  27. 10.1002/anie.200351647 / Angew. Chem., Int. Ed. (2003)
  28. 10.1021/ja00023a041 / J. Am. Chem. Soc. (1991)
  29. 10.1021/ja00134a027 / J. Am. Chem. Soc. (1995)
  30. 10.1016/S0379-6779(97)80881-8 / Synth. Met. (1997)
  31. 10.1021/ar00015a005 / Acc. Chem. Res. (1992)
  32. 10.1103/PhysRevB.57.12964 / Phys. Rev. B (1998)
  33. {'year': '1999', 'key': '2023063017172096000_c33', 'first-page': '101'} (1999)
  34. 10.1038/nmat978 / Nat. Mater. (2003)
  35. 10.1002/adma.200305200 / Adv. Mater. (Weinheim, Ger.) (2003)
  36. 10.1063/1.1702141 / J. Appl. Phys. (2004)
  37. {'year': '2003', 'key': '2023063017172096000_c37', 'first-page': '29'} (2003)
  38. 10.1063/1.123946 / Appl. Phys. Lett. (1999)
  39. 10.1063/1.1501450 / Appl. Phys. Lett. (2002)
  40. 10.1063/1.1690870 / Appl. Phys. Lett. (2004)
Dates
Type When
Created 19 years, 11 months ago (Sept. 6, 2005, 6:02 p.m.)
Deposited 2 years, 1 month ago (June 30, 2023, 2 p.m.)
Indexed 5 days, 12 hours ago (Aug. 23, 2025, 1:01 a.m.)
Issued 19 years, 11 months ago (Sept. 1, 2005)
Published 19 years, 11 months ago (Sept. 1, 2005)
Published Online 19 years, 11 months ago (Sept. 8, 2005)
Published Print 19 years, 11 months ago (Sept. 1, 2005)
Funders 0

None

@article{Anthopoulos_2005, title={Solution processible organic transistors and circuits based on a C70 methanofullerene}, volume={98}, ISSN={1089-7550}, url={http://dx.doi.org/10.1063/1.2034083}, DOI={10.1063/1.2034083}, number={5}, journal={Journal of Applied Physics}, publisher={AIP Publishing}, author={Anthopoulos, Thomas D. and de Leeuw, Dago M. and Cantatore, Eugenio and van ’t Hof, Patrick and Alma, Jan and Hummelen, Jan C.}, year={2005}, month=sep }