DOI: 10.1063/1.1954900. Electron spin resonance investigation of oxygen-vacancy-related defects in BaTiO3 thin films

Electron spin resonance investigation of oxygen-vacancy-related defects in BaTiO3 thin films

10.1063/1.1954900

Crossref journal-article

AIP Publishing

Applied Physics Letters (317)

Abstract

The Ti3+ center, based on a regular Ti site perturbed by an oxygen vacancy (VO), is identified by electron spin resonance (ESR) in textured BaTiO3 films. The center shows tetragonal symmetry along cubic ⟨100⟩ axes with g-factors: g‖=1.997, g⊥=1.904. The spectrum of this defect disappeared after the film annealing at 700°C in an O2 atmosphere. We describe the observed spectrum as Ti3+–VO couple defects or F+ center, which have never been observed in bulk BaTiO3. ESR is thus a unique tool to identify oxygen-vacancy-related defects, which have a large effect on the performance of ferroelectric films.

Bibliography

Laguta, V. V., Slipenyuk, A. M., Bykov, I. P., Glinchuk, M. D., Maglione, M., Michau, D., Rosa, J., & Jastrabik, L. (2005). Electron spin resonance investigation of oxygen-vacancy-related defects in BaTiO3 thin films. Applied Physics Letters, 87(2).

Authors 8

V. V. Laguta (first)
A. M. Slipenyuk (additional)
I. P. Bykov (additional)
M. D. Glinchuk (additional)
M. Maglione (additional)
D. Michau (additional)
J. Rosa (additional)
L. Jastrabik (additional)

References 14 Referenced 46

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Dates

Type	When
Created	20 years, 2 months ago (July 6, 2005, 8:33 p.m.)
Deposited	2 years, 2 months ago (July 2, 2023, 9:05 p.m.)
Indexed	1 month, 1 week ago (July 30, 2025, 6:45 a.m.)
Issued	20 years, 2 months ago (July 7, 2005)
Published	20 years, 2 months ago (July 7, 2005)
Published Online	20 years, 2 months ago (July 7, 2005)
Published Print	20 years, 1 month ago (July 11, 2005)

Funders 0

None

BibTeX

@article{Laguta_2005, title={Electron spin resonance investigation of oxygen-vacancy-related defects in BaTiO3 thin films}, volume={87}, ISSN={1077-3118}, url={http://dx.doi.org/10.1063/1.1954900}, DOI={10.1063/1.1954900}, number={2}, journal={Applied Physics Letters}, publisher={AIP Publishing}, author={Laguta, V. V. and Slipenyuk, A. M. and Bykov, I. P. and Glinchuk, M. D. and Maglione, M. and Michau, D. and Rosa, J. and Jastrabik, L.}, year={2005}, month=jul }

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