DOI: 10.1063/1.1894929. Signatures of the hydrogen bonding in the infrared bands of water

Signatures of the hydrogen bonding in the infrared bands of water

10.1063/1.1894929

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Infrared spectroscopy measurements have been completed over a wide range of frequencies allowing to measure the evolution of both intramolecular and intermolecular vibrational modes in water as a function of temperature. Emphasis is made on the high frequency OH stretching band and the so-called connectivity band that lies in the far infrared region. The substructures of the two infrared bands are analyzed in terms of different levels of connectivity of the water molecules, along the statements of the percolation model. Both band profiles appear to be related to the different degrees of connectivity of water molecules. Comparison of the data with the predictions of the percolation model shows good agreement as for the temperature evolution of liquid water. This work provides additional support to the interpretation of water bands substructures as signatures of its very specific connectivity pattern.

Bibliography

Brubach, J.-B., Mermet, A., Filabozzi, A., Gerschel, A., & Roy, P. (2005). Signatures of the hydrogen bonding in the infrared bands of water. The Journal of Chemical Physics, 122(18).

Authors 5

J.-B. Brubach (first)
A. Mermet (additional)
A. Filabozzi (additional)
A. Gerschel (additional)
P. Roy (additional)

References 27 Referenced 429

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Dates

Type	When
Created	20 years, 3 months ago (May 6, 2005, 6:12 p.m.)
Deposited	2 years ago (July 31, 2023, 5:46 p.m.)
Indexed	1 week, 1 day ago (Aug. 12, 2025, 5:47 p.m.)
Issued	20 years, 3 months ago (May 8, 2005)
Published	20 years, 3 months ago (May 8, 2005)
Published Online	20 years, 3 months ago (May 9, 2005)
Published Print	20 years, 3 months ago (May 8, 2005)

Funders 0

None

BibTeX

@article{Brubach_2005, title={Signatures of the hydrogen bonding in the infrared bands of water}, volume={122}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1894929}, DOI={10.1063/1.1894929}, number={18}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Brubach, J.-B. and Mermet, A. and Filabozzi, A. and Gerschel, A. and Roy, P.}, year={2005}, month=may }

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