Abstract
We report on the crystallization of colloidal crystals comprising of charged particles with different size ratio dispersed in thoroughly deionized water. Single components were characterized carefully and their nucleation behavior was investigated before the preparation of mixtures. Mixtures investigated at constant particle number densities showed body centred cubic structure, conductivity, and shear moduli comply with the assumption of a randomly substituted crystal. Most importantly, for the first time we obtain the dependence of the nucleation rate densities in dependence on the composition and (for one fixed composition) the particle number density. The process of nucleation in random substitutional crystals is found to be similar to the one-component case.
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Dates
Type | When |
---|---|
Created | 20 years, 4 months ago (April 7, 2005, 6:19 p.m.) |
Deposited | 2 years ago (July 31, 2023, 4:09 p.m.) |
Indexed | 3 weeks, 3 days ago (July 30, 2025, 6:45 a.m.) |
Issued | 20 years, 4 months ago (April 8, 2005) |
Published | 20 years, 4 months ago (April 8, 2005) |
Published Online | 20 years, 4 months ago (April 11, 2005) |
Published Print | 20 years, 4 months ago (April 8, 2005) |
@article{Wette_2005, title={Crystallization in charged two-component suspensions}, volume={122}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1872752}, DOI={10.1063/1.1872752}, number={14}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Wette, Patrick and Schöpe, Hans Joachim and Palberg, Thomas}, year={2005}, month=apr }