DOI: 10.1063/1.1841014. Ground-State Molecular Constants of Hydrogen Sulfide

Ground-State Molecular Constants of Hydrogen Sulfide

10.1063/1.1841014

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

A simultaneous analysis of 185 distinct ground-state combination differences taken from the (1, 1, 1) and (2, 1, 0) absorption bands of H232S together with the two microwave transitions reported by Burrus and Gordy, yielded the following values for the ground-state molecular constants (in cm−1): A0=10.3599±0.0004, B0=9.0156±0.0005, C0=4.7315±0.0004, τaaaa=—(8.06±0.13)×10−3, τbbbb=—(4.84±0.04)×10−3, τaabb=+(4.57±0.10)×10−3, τabab=—(1.31±0.06)×10−3, H0K=—(4.6±1.6)×10−8 (with simultaneous confidence intervals at the 95% level). Equilibrium structural parameters determined from the values of A and B in the (1, 1, 1) and ground states are: re=1.3356 and φ=92°07′.

Bibliography

Edwards, T. H., Moncur, N. K., & Snyder, L. E. (1967). Ground-State Molecular Constants of Hydrogen Sulfide. The Journal of Chemical Physics, 46(6), 2139â2142.

Authors 3

T. H. Edwards (first)
N. K. Moncur (additional)
L. E. Snyder (additional)

References 20 Referenced 102

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{'key': '2024020902015924100_r12'}
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{'key': '2024020902015924100_r16'}
10.1016/0031-9163(66)90299-X / Phys. Letters (1966)
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Dates

Type	When
Created	20 years, 7 months ago (Jan. 5, 2005, 11:35 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 9:02 p.m.)
Indexed	1 year, 6 months ago (Feb. 11, 2024, 1:21 a.m.)
Issued	58 years, 5 months ago (March 15, 1967)
Published	58 years, 5 months ago (March 15, 1967)
Published Print	58 years, 5 months ago (March 15, 1967)

Funders 0

None

BibTeX

@article{Edwards_1967, title={Ground-State Molecular Constants of Hydrogen Sulfide}, volume={46}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1841014}, DOI={10.1063/1.1841014}, number={6}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Edwards, T. H. and Moncur, N. K. and Snyder, L. E.}, year={1967}, month=mar, pages={2139–2142} }

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