Abstract
The influence of molecular linear and nonlinear polarizability, anisotropy, shape, radial and angular correlations, and other microscopic factors on anisotropic light scattering is discussed for some models of a liquid within the framework of statistical—molecular theory. An effective optical anisotropy Δ2 is introduced and computed numerically for several liquids from the experimental depolarization ratio Du and optical birefringence constant Bλ; for strongly anisotropic substances, this yields Δ2 values almost twice smaller than those determined from the anisotropic Rayleigh ratio Ranis. Theoretical, numerical computations of Δ2 basing on the ellipsoidal Lorentz and Onsager—Scholte models result in values close to those from Du and Bλ. Finally, the isotropic and anisotropic parts of the refractive index variation due to intense laser light are related, respectively, with the isotropic and anisotropic Rayleigh ratios, by means of which numerical computations are made for various liquids.
References
82
Referenced
92
{'key': '2024020902111762400_r1', 'first-page': '205', 'volume': '25', 'year': '1908', 'journal-title': 'Ann. Physik'}
/ Ann. Physik (1908){'key': '2024020902111762400_r2', 'first-page': '1275', 'volume': '33', 'year': '1910', 'journal-title': 'Ann. Physik'}
/ Ann. Physik (1910)10.1063/1.1740668
/ J. Chem. Phys. (1955){'key': '2024020902111762400_r4'}
{'key': '2024020902111762400_r5', 'first-page': '144', 'volume': '13', 'year': '1945', 'journal-title': 'J. Chem. Phys.'}
/ J. Chem. Phys. (1945){'key': '2024020902111762400_r6', 'first-page': '309', 'volume': '1', 'year': '1958', 'journal-title': 'Advan. Chem. Phys.'}
/ Advan. Chem. Phys. (1958){'key': '2024020902111762400_r7', 'first-page': '387', 'volume': 'A258', 'year': '1965', 'journal-title': 'Phil. Trans. Roy. Soc. (London)'}
/ Phil. Trans. Roy. Soc. (London) (1965)10.1063/1.1696324
/ J. Chem. Phys. (1965){'key': '2024020902111762400_r9', 'first-page': '168', 'volume': '139', 'year': '1965', 'journal-title': 'Phys. Rev.'}
/ Phys. Rev. (1965)10.1007/BF01391926
/ Z. Physik (1927){'key': '2024020902111762400_r11'}
{'key': '2024020902111762400_r11a'}
{'key': '2024020902111762400_r12'}
{'key': '2024020902111762400_r12a'}
{'key': '2024020902111762400_r13', 'first-page': '489', 'volume': '17', 'year': '1947', 'journal-title': 'Zh. Eksperim. i Teor. Fiz.'}
/ Zh. Eksperim. i Teor. Fiz. (1947)10.1051/jphysrad:0195600170102100
/ J. Phys. Radium (1956)10.1016/S0031-8914(56)90002-7
/ Physica (1956){'key': '2024020902111762400_r15a', 'first-page': '253', 'volume': '23', 'year': '1957'}
(1957){'key': '2024020902111762400_r16', 'first-page': '215', 'volume': '6', 'year': '1958', 'journal-title': 'Bull. Acad. Polon. Sci. Sér. Sci. Math. Astron. Phys.'}
/ Bull. Acad. Polon. Sci. Sér. Sci. Math. Astron. Phys. (1958){'key': '2024020902111762400_r17', 'first-page': '149', 'volume': '19', 'year': '1960', 'journal-title': 'Acta Phys. Polon.'}
/ Acta Phys. Polon. (1960){'key': '2024020902111762400_r17a', 'first-page': '3', 'volume': '11', 'year': '1964', 'journal-title': 'Poznan. Towarz. Przyjacol Nauk, Wydzial Mat. Przyrod. Prace Komisji Mat. Przyrod.'}
/ Poznan. Towarz. Przyjacol Nauk, Wydzial Mat. Przyrod. Prace Komisji Mat. Przyrod. (1964)10.1063/1.1696217
/ J. Chem. Phys. (1965){'key': '2024020902111762400_r19', 'first-page': '1162', 'volume': '136', 'year': '1961', 'journal-title': 'Dokl. Akad. Nauk'}
/ Dokl. Akad. Nauk (1961){'key': '2024020902111762400_r19a', 'first-page': '782', 'volume': '7', 'year': '1962', 'journal-title': 'Ukr. Fiz. Zh.'}
/ Ukr. Fiz. Zh. (1962)10.1063/1.1727306
/ J. Chem. Phys. (1966){'key': '2024020902111762400_r21', 'first-page': '711', 'volume': '19', 'year': '1960', 'journal-title': 'Acta Phys. Polon.'}
/ Acta Phys. Polon. (1960){'key': '2024020902111762400_r21a', 'first-page': '51', 'volume': '11', 'year': '1964', 'journal-title': 'Poznan. Towarz. Przyjcol Nauk, Wydzial Mat. Przyrod. Prace Komisji Mat. Przyrod.'}
/ Poznan. Towarz. Przyjcol Nauk, Wydzial Mat. Przyrod. Prace Komisji Mat. Przyrod. (1964)10.1039/tf9575300884
/ Trans. Faraday Soc. (1957){'key': '2024020902111762400_r23', 'first-page': '159', 'volume': '10', 'year': '1928', 'journal-title': 'Ann. Phys. (Paris)'}
/ Ann. Phys. (Paris) (1928){'key': '2024020902111762400_r23a', 'first-page': '1063', 'volume': '6', 'year': '1961', 'journal-title': 'Ann. Phys. (Paris)'}
/ Ann. Phys. (Paris) (1961){'key': '2024020902111762400_r24', 'first-page': '573', 'volume': '19', 'year': '1960', 'journal-title': 'Acta Phys. Polon.'}
/ Acta Phys. Polon. (1960){'key': '2024020902111762400_r24a', 'first-page': '83', 'volume': '20', 'year': '1961', 'journal-title': 'Acta Phys. Pol.'}
/ Acta Phys. Pol. (1961){'key': '2024020902111762400_r25', 'first-page': '43', 'volume': '17', 'year': '1962–1963', 'journal-title': 'Bull. Soc. Amis Sci. Lettres Poznan, Ser. B'}
/ Bull. Soc. Amis Sci. Lettres Poznan, Ser. B (1962–1963){'key': '2024020902111762400_r25a', 'first-page': '819', 'volume': '23', 'year': '1963', 'journal-title': 'Acta Phys. Polon.'}
/ Acta Phys. Polon. (1963){'key': '2024020902111762400_r25b', 'first-page': '85', 'volume': '25', 'year': '1964', 'journal-title': 'Acta Phys. Pol.'}
/ Acta Phys. Pol. (1964){'key': '2024020902111762400_r26', 'first-page': '35', 'volume': '38', 'year': '1966', 'journal-title': 'Croat. Chem. Acta'}
/ Croat. Chem. Acta (1966)10.1016/S0031-8914(37)80202-5
/ Physica (1937)10.1021/j150416a009
/ J. Chem. Phys. (1942)10.1016/S0031-8914(42)90118-6
/ Physica (1942){'key': '2024020902111762400_r28', 'first-page': '65', 'volume': '22', 'year': '1962', 'journal-title': 'Acta Phys. Polon.'}
/ Acta Phys. Polon. (1962){'key': '2024020902111762400_r28a', 'first-page': '95', 'volume': '28', 'year': '1965', 'journal-title': 'Acta Phys. Pol.'}
/ Acta Phys. Pol. (1965)10.1016/0031-8914(65)90072-8
/ Physica (1965){'key': '2024020902111762400_r30', 'first-page': '508', 'volume': 'A221', 'year': '1954', 'journal-title': 'Proc. Roy. Soc. (London)'}
/ Proc. Roy. Soc. (London) (1954)10.1039/TF9555101173
/ Trans. Faraday Soc. (1955)10.1063/1.1706508
/ Phys. Fluids (1962)10.1063/1.1750922
/ J. Chem. Phys. (1941)10.1039/tf9494500974
/ Trans. Faraday Soc. (1949){'key': '2024020902111762400_r34'}
{'key': '2024020902111762400_r35', 'first-page': '433', 'volume': '20', 'year': '1961', 'journal-title': 'Acta Phys. Polon.'}
/ Acta Phys. Polon. (1961)10.1016/0031-8914(62)90038-1
/ Physica (1962)10.1063/1.1734300
/ J. Chem. Phys. (1963)10.1063/1.1696342
/ J. Chem. Phys. (1965)10.1103/PhysRev.137.A369
/ Phys. Rev. (1965)10.1063/1.1725590
/ J. Chem. Phys. (1964){'key': '2024020902111762400_r38', 'first-page': '299', 'volume': '22', 'year': '1962', 'journal-title': 'Acta Phys. Polon.'}
/ Acta Phys. Polon. (1962){'key': '2024020902111762400_r39', 'first-page': '683', 'volume': '30', 'year': '1966', 'journal-title': 'Acta Phys. Polon.'}
/ Acta Phys. Polon. (1966)10.1088/0370-1328/90/3/330
/ Proc. Phys. Soc. (London) (1967)10.1039/tf9585400954
/ Trans. Faraday Soc. (1958)10.1080/14786440308565093
/ Phil. Mag. (1928){'key': '2024020902111762400_r42', 'first-page': '344', 'volume': 'B69', 'year': '1956', 'journal-title': 'Proc. Phys. Soc. (London)'}
/ Proc. Phys. Soc. (London) (1956)10.1039/tf9646001539
/ Trans. Faraday Soc. (1964){'key': '2024020902111762400_r44', 'first-page': '264', 'volume': '262', 'year': '1966', 'journal-title': 'Compt. Rend.'}
/ Compt. Rend. (1966){'key': '2024020902111762400_r45', 'first-page': '30', 'volume': '58', 'year': '1940', 'journal-title': 'Phys. Rev.'}
/ Phys. Rev. (1940)10.1103/PhysRev.62.261
/ Phys. Rev. (1942)10.1103/PhysRevLett.12.507
/ Phys. Rev. Letters (1964){'key': '2024020902111762400_r46a', 'first-page': '2039', 'volume': '258', 'year': '1964', 'journal-title': 'Compt. Rend.'}
/ Compt. Rend. (1964)10.1103/PhysRevLett.13.479
/ Phys. Rev. Letters (1964)10.1016/0031-9163(66)90749-9
/ Phys. Letters (1966){'key': '2024020902111762400_r48'}
{'key': '2024020902111762400_r48a'}
{'key': '2024020902111762400_r49', 'first-page': '3741', 'volume': '40', 'year': '1964', 'journal-title': 'J. Chem. Phys.'}
/ J. Chem. Phys. (1964)10.1063/1.1727126
/ J. Chem. Phys. (1966)10.1103/PhysRevLett.14.533
/ Phys. Rev. Letters (1965){'key': '2024020902111762400_r50a'}
10.1039/qr9591300183
/ Quart. Rev. (London) (1959)10.1080/00268976500100731
/ Mol. Phys. (1965)10.1103/RevModPhys.38.690
/ Rev. Mod. Phys. (1966)10.1080/00268976600101201
/ Mol. Phys. (1966)10.1063/1.1731405
/ J. Chem. Phys. (1960){'key': '2024020902111762400_r56', 'first-page': '389', 'volume': '24', 'year': '1963', 'journal-title': 'Acta Phys. Polon.'}
/ Acta Phys. Polon. (1963){'key': '2024020902111762400_r56a', 'first-page': '457', 'volume': '27', 'year': '1965', 'journal-title': 'Acta Phys. Pol.'}
/ Acta Phys. Pol. (1965){'key': '2024020902111762400_r57', 'first-page': '851', 'volume': '30', 'year': '1966', 'journal-title': 'Acta Phys. Polon.'}
/ Acta Phys. Polon. (1966)
Dates
Type | When |
---|---|
Created | 20 years, 7 months ago (Jan. 5, 2005, 11:35 p.m.) |
Deposited | 1 year, 6 months ago (Feb. 8, 2024, 9:11 p.m.) |
Indexed | 1 year, 6 months ago (Feb. 10, 2024, 3:34 a.m.) |
Issued | 58 years, 3 months ago (May 15, 1967) |
Published | 58 years, 3 months ago (May 15, 1967) |
Published Print | 58 years, 3 months ago (May 15, 1967) |
@article{Kielich_1967, title={Role of Molecular Interaction in Anisotropic Light Scattering by Liquids}, volume={46}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1840491}, DOI={10.1063/1.1840491}, number={10}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Kielich, Stanisℏaw}, year={1967}, month=may, pages={4090–4099} }