DOI: 10.1063/1.1840375. Restricted Rotation in Solid Deuteromethanes

Restricted Rotation in Solid Deuteromethanes

10.1063/1.1840375

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The theory of Nagamiya for restricted rotation in solid methane is extended to all of the partially deuterated species and applied to the experimental heat-capacity data of Colwell, Gill, and Morrison, which show anomalously high values in the range below 4°K. Agreement with these data is obtained for reasonable values of the energy parameters; also the total entropy of each anomaly is predicted.

Bibliography

Hopkins, H. P., Kasper, J. V. V., & Pitzer, K. S. (1967). Restricted Rotation in Solid Deuteromethanes. The Journal of Chemical Physics, 46(1), 218â220.

Authors 3

Harry P. Hopkins (first)
Jerome V. V. Kasper (additional)
Kenneth S. Pitzer (additional)

References 6 Referenced 15

{'key': '2024020902050124000_r1'}
10.1016/S0031-8914(37)80207-4 / Physica (1937)
10.1063/1.1696393 / J. Chem. Phys. (1965)
10.1016/0031-8914(65)90153-9 / Physica (1965)
10.1143/ptp/6.5.702 / Progr. Theoret. Phys. (Kyoto) (1951)
10.1063/1.1749653 / J. Chem. Phys. (1935)

Dates

Type	When
Created	20 years, 7 months ago (Jan. 5, 2005, 11:35 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 9:05 p.m.)
Indexed	1 year, 6 months ago (Feb. 9, 2024, 3:46 p.m.)
Issued	58 years, 7 months ago (Jan. 1, 1967)
Published	58 years, 7 months ago (Jan. 1, 1967)
Published Print	58 years, 7 months ago (Jan. 1, 1967)

Funders 0

None

BibTeX

@article{Hopkins_1967, title={Restricted Rotation in Solid Deuteromethanes}, volume={46}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1840375}, DOI={10.1063/1.1840375}, number={1}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Hopkins, Harry P. and Kasper, Jerome V. V. and Pitzer, Kenneth S.}, year={1967}, month=jan, pages={218–220} }

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