DOI: 10.1063/1.1836756. The proper structure of cubic ice confined in mesopores

The proper structure of cubic ice confined in mesopores

10.1063/1.1836756

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

To examine the reason for the formation and the structure of cubic ice in a restricted space, we measured the powder x-ray diffraction patterns of cubic ice formed within the mesopores of porous silicas as a function of pore size (4–70 nm). The results strongly suggest that cubic ice formed in the mesopores does not take a cubic structure as envisaged by König. It may be actually composed of very small crystallites of hexagonal ice that contains a large amount of growth faults depending on the crystallite size, that is, ice with disordered stacking sequence. Suppression of crystal growth of ice in the mesopores seems to be a vital factor for the formation and the stability of cubic ice.

Bibliography

Morishige, K., & Uematsu, H. (2005). The proper structure of cubic ice confined in mesopores. The Journal of Chemical Physics, 122(4).

Authors 2

Kunimitsu Morishige (first)
Hiroaki Uematsu (additional)

References 29 Referenced 95

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Dates

Type	When
Created	20 years, 7 months ago (Jan. 15, 2005, 11 a.m.)
Deposited	2 years, 1 month ago (July 8, 2023, 8:06 p.m.)
Indexed	3 weeks, 1 day ago (July 30, 2025, 8:24 p.m.)
Issued	20 years, 7 months ago (Jan. 7, 2005)
Published	20 years, 7 months ago (Jan. 7, 2005)
Published Online	20 years, 7 months ago (Jan. 7, 2005)
Published Print	20 years, 6 months ago (Jan. 22, 2005)

Funders 0

None

BibTeX

@article{Morishige_2005, title={The proper structure of cubic ice confined in mesopores}, volume={122}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1836756}, DOI={10.1063/1.1836756}, number={4}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Morishige, Kunimitsu and Uematsu, Hiroaki}, year={2005}, month=jan }

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