Abstract
We demonstrate high-efficiency organic photovoltaic cells by stacking two hybrid planar-mixed molecular heterojunction cells in series. Absorption of incident light is maximized by locating the subcell tuned to absorb long-wavelength light nearest to the transparent anode, and tuning the second subcell closest to the reflecting metal cathode to preferentially absorb short-wavelength solar energy. Using the donor, copper phthalocyanine, and the acceptor, C60, we achieve a maximum power conversion efficiency of ηP=(5.7±0.3)% under 1 sun simulated AM1.5G solar illumination. An open-circuit voltage of VOC⩽1.2V is obtained, doubling that of a single cell. Analytical models suggest that power conversion efficiencies exceeding 6.5% can be obtained by this architecture.
References
17
Referenced
511
10.1063/1.1534621
/ J. Appl. Phys. (2003)10.1002/1616-3028(200102)11:1<15::AID-ADFM15>3.0.CO;2-A
/ Adv. Funct. Mater. (2001)10.1063/1.96937
/ Appl. Phys. Lett. (1986)10.1038/376498a0
/ Nature (London) (1995)10.1126/science.270.5243.1789
/ Science (1995)10.1063/1.1384001
/ Appl. Phys. Lett. (2001)10.1063/1.1345834
/ Appl. Phys. Lett. (2001)10.1063/1.1457531
/ Appl. Phys. Lett. (2002)10.1002/adfm.200390011
/ Adv. Funct. Mater. (2003)10.1063/1.1713036
/ Appl. Phys. Lett. (2004)10.1063/1.1755833
/ Appl. Phys. Lett. (2004)10.1007/s00339-003-2494-9
/ Appl. Phys. A: Mater. Sci. Process. (2004){'key': '2024020404460085300_c13', 'volume-title': 'Adv. Mater.'}
/ Adv. Mater.{'key': '2024020404460085300_c14', 'first-page': '327', 'volume': '1990', 'year': '1990', 'journal-title': 'Chem. Lett.'}
/ Chem. Lett. (1990)10.1063/1.126433
/ Appl. Phys. Lett. (2000)10.1063/1.370757
/ J. Appl. Phys. (1999)10.1002/pip.533
/ Prog. Photovoltaics (2004)
Dates
Type | When |
---|---|
Created | 20 years, 8 months ago (Dec. 8, 2004, 6:42 p.m.) |
Deposited | 1 year, 7 months ago (Feb. 3, 2024, 11:46 p.m.) |
Indexed | 2 months, 3 weeks ago (June 14, 2025, 10:46 a.m.) |
Issued | 20 years, 8 months ago (Dec. 6, 2004) |
Published | 20 years, 8 months ago (Dec. 6, 2004) |
Published Print | 20 years, 8 months ago (Dec. 6, 2004) |
@article{Xue_2004, title={Asymmetric tandem organic photovoltaic cells with hybrid planar-mixed molecular heterojunctions}, volume={85}, ISSN={1077-3118}, url={http://dx.doi.org/10.1063/1.1829776}, DOI={10.1063/1.1829776}, number={23}, journal={Applied Physics Letters}, publisher={AIP Publishing}, author={Xue, Jiangeng and Uchida, Soichi and Rand, Barry P. and Forrest, Stephen R.}, year={2004}, month=dec, pages={5757–5759} }