Abstract
Grazing incidence x-ray diffraction, x-ray reflectivity and atomic force microscopy have been performed to study the structure of pentacene thin films on oxidized Si substrates from submonolayer to multilayer coverages. The volume of the unit cell in the thin film phase is almost identical to that of the bulk phase, thus the molecular packing efficiency is effectively the same in both phases. The structure forming from the first monolayer remains the same for films at least 190Å thick. The in-plane structure of the submonolayer islands also remains unchanged within a substrate temperature range of 0<Tsub<45°C while the island size changes by more than a factor of 4.
References
15
Referenced
158
10.1002/1521-4095(20020116)14:2<99::AID-ADMA99>3.0.CO;2-9
/ Adv. Mater. (Weinheim, Ger.) (2002)10.1107/S0365110X62000699
/ Acta Crystallogr. (1962)10.1002/(SICI)1521-3765(19991105)5:11<3399::AID-CHEM3399>3.0.CO;2-V
/ Chem.-Eur. J. (1999)10.1063/1.363032
/ J. Appl. Phys. (1996)10.1063/1.352004
/ J. Appl. Phys. (1992)10.1021/ja049726b
/ J. Am. Chem. Soc. (2004)10.1107/S0021889803025093
/ J. Appl. Crystallogr. (2004){'key': '2024020404345904000_c8', 'first-page': '397', 'volume': '734', 'year': '2003', 'journal-title': 'Mater. Res. Soc. Symp. Proc.'}
/ Mater. Res. Soc. Symp. Proc. (2003)10.1103/PhysRevB.67.125406
/ Phys. Rev. B (2003)10.1016/j.orgel.2004.05.001
/ Org. Electron. (2004)10.1103/PhysRevLett.56.1144
/ Phys. Rev. Lett. (1986)10.1103/PhysRevB.68.115428
/ Phys. Rev. B (2003){'key': '2024020404345904000_c13', 'volume-title': 'International Tables for X-Ray Crystallography', 'author': 'I. U. of Crystallography', 'year': '1952'}
/ International Tables for X-Ray Crystallography by I. U. of Crystallography (1952)10.1063/1.1491009
/ Appl. Phys. Lett. (2002)10.1088/0034-4885/47/4/002
/ Rep. Prog. Phys. (1984)
Dates
Type | When |
---|---|
Created | 20 years, 9 months ago (Nov. 23, 2004, 10:21 p.m.) |
Deposited | 1 year, 7 months ago (Feb. 3, 2024, 11:35 p.m.) |
Indexed | 5 days, 2 hours ago (Sept. 2, 2025, 6:37 a.m.) |
Issued | 20 years, 9 months ago (Nov. 22, 2004) |
Published | 20 years, 9 months ago (Nov. 22, 2004) |
Published Print | 20 years, 9 months ago (Nov. 22, 2004) |
@article{Ruiz_2004, title={Structure of pentacene thin films}, volume={85}, ISSN={1077-3118}, url={http://dx.doi.org/10.1063/1.1826229}, DOI={10.1063/1.1826229}, number={21}, journal={Applied Physics Letters}, publisher={AIP Publishing}, author={Ruiz, Ricardo and Mayer, Alex C. and Malliaras, George G. and Nickel, Bert and Scoles, Giacinto and Kazimirov, Alexander and Kim, Hyunjung and Headrick, Randall L. and Islam, Zahirul}, year={2004}, month=nov, pages={4926–4928} }