DOI: 10.1063/1.1814052. Enhanced infrared absorption spectra of self-assembled alkanethiol monolayers using the extraordinary infrared transmission of metallic arrays of subwavelength apertures

Enhanced infrared absorption spectra of self-assembled alkanethiol monolayers using the extraordinary infrared transmission of metallic arrays of subwavelength apertures

10.1063/1.1814052

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The surface-plasmon-mediated, extraordinary transmission of metallic arrays of subwavelength apertures has been used as the light source for absorption studies of self-assembled monolayers on metal. Enhanced infrared absorption spectra of a sequence of alkanethiol self-assembled monolayers on copper were recorded for carbon chain lengths varying from 8 to 18 atoms. Transition positions and intensities are presented over a large range of the infrared region. The connection between the vibrational modes of the CH2 wagging progression and the infinite methylene chain is explored using a traditional coupled oscillator approach and a new cluster perspective.

Bibliography

Rodriguez, K. R., Shah, S., Williams, S. M., Teeters-Kennedy, S., & Coe, J. V. (2004). Enhanced infrared absorption spectra of self-assembled alkanethiol monolayers using the extraordinary infrared transmission of metallic arrays of subwavelength apertures. The Journal of Chemical Physics, 121(18), 8671â8675.

Authors 5

Kenneth R. Rodriguez (first)
Summit Shah (additional)
Shaun M. Williams (additional)
Shannon Teeters-Kennedy (additional)
James V. Coe (additional)

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Dates

Type	When
Created	20 years, 9 months ago (Nov. 2, 2004, 6:05 a.m.)
Deposited	2 years, 1 month ago (July 12, 2023, 3:23 p.m.)
Indexed	11 months ago (Sept. 25, 2024, 7:04 a.m.)
Issued	20 years, 10 months ago (Oct. 29, 2004)
Published	20 years, 10 months ago (Oct. 29, 2004)
Published Online	20 years, 10 months ago (Oct. 29, 2004)
Published Print	20 years, 9 months ago (Nov. 8, 2004)

Funders 0

None

BibTeX

@article{Rodriguez_2004, title={Enhanced infrared absorption spectra of self-assembled alkanethiol monolayers using the extraordinary infrared transmission of metallic arrays of subwavelength apertures}, volume={121}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1814052}, DOI={10.1063/1.1814052}, number={18}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Rodriguez, Kenneth R. and Shah, Summit and Williams, Shaun M. and Teeters-Kennedy, Shannon and Coe, James V.}, year={2004}, month=oct, pages={8671–8675} }

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