Abstract
Fluorescent semiconductor materials doped with rare earth ions have been synthesized by flocculation of colloidal titania nanosheets, Ti0.91O2, with Eu3+ or Tb3+ ions. The composites had a lamellar structure with a gallery height of 1.06nm, accommodating rare earth ions between the nanosheets with a doping concentration as high as 10±1mol%. The composite with Eu3+ exhibited intense characteristic emission from Eu3+ either by exciting the Ti0.91O2 host with UV light (λ<350nm) or by directly exciting Eu3+ at a longer wavelength where there was no absorption by Ti0.91O2. This indicates that nonradiative energy transfer from the Ti0.91O2 host to Eu3+ can take place in this system. In contrast, no energy transfer was observed in the composite with Tb3+.
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Dates
Type | When |
---|---|
Created | 20 years, 9 months ago (Nov. 3, 2004, 6:48 p.m.) |
Deposited | 1 year, 6 months ago (Feb. 3, 2024, 11:21 p.m.) |
Indexed | 1 year, 3 months ago (May 20, 2024, 3:16 p.m.) |
Issued | 20 years, 9 months ago (Nov. 1, 2004) |
Published | 20 years, 9 months ago (Nov. 1, 2004) |
Published Print | 20 years, 9 months ago (Nov. 1, 2004) |
@article{Xin_2004, title={Photoluminescence properties of lamellar aggregates of titania nanosheets accommodating rare earth ions}, volume={85}, ISSN={1077-3118}, url={http://dx.doi.org/10.1063/1.1812811}, DOI={10.1063/1.1812811}, number={18}, journal={Applied Physics Letters}, publisher={AIP Publishing}, author={Xin, Hao and Ma, Renzhi and Wang, Lianzhou and Ebina, Yasuo and Takada, Kazunori and Sasaki, Takayoshi}, year={2004}, month=nov, pages={4187–4189} }