Abstract
The carrier transport of carefully purified regioregular poly(3-hexylthiophene) films has been studied using time-of-flight photocurrent measurements. We find balanced ambipolar transport with a room-temperature mobility for holes of 3×10−4cm2V−1s−1 and for electrons of 1.5×10−4cm2V−1s−1 at electric fields ⩾105V∕cm. The transport is relatively field independent and weakly temperature dependent, pointing to a high degree of chemical regioregularity and purity. These factors make poly(3-hexylthiophene) attractive for use in a range of electronic applications.
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Dates
Type | When |
---|---|
Created | 20 years, 9 months ago (Nov. 2, 2004, 11:05 a.m.) |
Deposited | 1 year, 6 months ago (Feb. 3, 2024, 11:14 p.m.) |
Indexed | 1 month, 1 week ago (July 16, 2025, 9:12 a.m.) |
Issued | 20 years, 10 months ago (Oct. 25, 2004) |
Published | 20 years, 10 months ago (Oct. 25, 2004) |
Published Print | 20 years, 10 months ago (Oct. 25, 2004) |
@article{Choulis_2004, title={High ambipolar and balanced carrier mobility in regioregular poly(3-hexylthiophene)}, volume={85}, ISSN={1077-3118}, url={http://dx.doi.org/10.1063/1.1805175}, DOI={10.1063/1.1805175}, number={17}, journal={Applied Physics Letters}, publisher={AIP Publishing}, author={Choulis, S. A. and Kim, Y. and Nelson, J. and Bradley, D. D. C. and Giles, M. and Shkunov, M. and McCulloch, I.}, year={2004}, month=oct, pages={3890–3892} }