DOI: 10.1063/1.1782253. Free-standing subnanometer graphite sheets

Free-standing subnanometer graphite sheets

10.1063/1.1782253

Crossref journal-article

AIP Publishing

Applied Physics Letters (317)

Abstract

Free-standing graphite sheets with thickness less than 1nm, “carbon nanosheets,” were synthesized on a variety of substrates by radio-frequency plasma-enhanced chemical vapor deposition without any catalyst or special substrate treatment. The nanosheets consist of one to three graphene layers with a large smooth surface topography, standing roughly vertical to the substrate. Due to the atomic thickness and corrugated nature of nanosheets, low-energy vibrational modes are present in the Raman spectra. The low turn-on field of 4.7 V/μm for electron field emission suggests that the carbon nanosheets could be used as a potential edge emitter.

Bibliography

Wang, J. J., Zhu, M. Y., Outlaw, R. A., Zhao, X., Manos, D. M., Holloway, B. C., & Mammana, V. P. (2004). Free-standing subnanometer graphite sheets. Applied Physics Letters, 85(7), 1265â1267.

Authors 7

J. J. Wang (first)
M. Y. Zhu (additional)
R. A. Outlaw (additional)
X. Zhao (additional)
D. M. Manos (additional)
B. C. Holloway (additional)
V. P. Mammana (additional)

References 25 Referenced 424

10.1016/0378-4363(80)90275-2 / Physica B & C (1980)
10.1103/PhysRevB.26.4514 / Phys. Rev. B (1982)
10.1103/PhysRevB.46.139 / Phys. Rev. B (1992)
10.1016/0009-2614(93)87205-H / Chem. Phys. Lett. (1993)
10.1126/science.275.5297.187 / Science (1997)
10.1080/000187300413184 / Adv. Phys. (2000)
10.1103/PhysRevB.54.17954 / Phys. Rev. B (1996)
10.1103/PhysRevB.59.8271 / Phys. Rev. B (1999)
10.1103/PhysRevB.63.134421 / Phys. Rev. B (2001)
10.1038/358220a0 / Nature (London) (1992)
10.1016/S0008-6223(96)00139-X / Carbon (1997)
10.1021/jp953400v / J. Phys. Chem. (1996)
10.1016/S0009-2614(02)00430-X / Chem. Phys. Lett. (2002)
10.1016/S0169-4332(03)00293-9 / Appl. Surf. Sci. (2003)
10.1126/science.1078842 / Science (2003)
{'key': '2024020403430428300_c16', 'volume-title': 'Principles of Plasma Discharges and Materials Processing', 'year': '1994'} / Principles of Plasma Discharges and Materials Processing (1994)
10.1063/1.1674108 / J. Chem. Phys. (1970)
10.1103/PhysRevB.20.392 / Phys. Rev. B (1979)
10.1103/PhysRevB.49.11433 / Phys. Rev. B (1994)
10.1016/S0009-2614(00)01236-7 / Chem. Phys. Lett. (2000)
10.1063/1.1582352 / Appl. Phys. Lett. (2003)
10.1103/PhysRevB.66.235424 / Phys. Rev. B (2002)
10.1016/0025-5416(77)90029-5 / Mater. Sci. Eng. (1977)
10.1016/S0038-1101(00)00213-6 / Solid-State Electron. (2001)
10.1016/S0038-1101(00)00209-4 / Solid-State Electron. (2001)

Dates

Type	When
Created	21 years ago (Aug. 10, 2004, 6:58 p.m.)
Deposited	1 year, 6 months ago (Feb. 3, 2024, 10:43 p.m.)
Indexed	2 weeks, 1 day ago (Aug. 19, 2025, 6:30 a.m.)
Issued	21 years ago (Aug. 16, 2004)
Published	21 years ago (Aug. 16, 2004)
Published Print	21 years ago (Aug. 16, 2004)

Funders 0

None

BibTeX

@article{Wang_2004, title={Free-standing subnanometer graphite sheets}, volume={85}, ISSN={1077-3118}, url={http://dx.doi.org/10.1063/1.1782253}, DOI={10.1063/1.1782253}, number={7}, journal={Applied Physics Letters}, publisher={AIP Publishing}, author={Wang, J. J. and Zhu, M. Y. and Outlaw, R. A. and Zhao, X. and Manos, D. M. and Holloway, B. C. and Mammana, V. P.}, year={2004}, month=aug, pages={1265–1267} }

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