DOI: 10.1063/1.1776916. Absorption Spectrum of Gaseous F- and Electron Affinities of the Halogen Atoms

Absorption Spectrum of Gaseous F- and Electron Affinities of the Halogen Atoms

10.1063/1.1776916

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The absorption spectrum of gaseous fluoride ion has been observed in shock-heated vapors of CsF, RbF, and KF. The spectrum is a continuum with two sharp thresholds at 3595 and 3542 Å, similar to those of the other halide ions. The electron affinity determined from the low-energy threshold is 3.448±0.005 eV. The cross-section for photodetachment at 3565 Å is about 2.5±2×10−18 cm2 and at 3525, about 3.3±2×10−18 cm2. The electron affinities of chlorine, bromine and iodine are revised, respectively, to 3.613, 3.363, and 3.063 eV, all with uncertainties of 0.003 eV.

Bibliography

Berry, R. S., & Reimann, C. W. (1963). Absorption Spectrum of Gaseous F- and Electron Affinities of the Halogen Atoms. The Journal of Chemical Physics, 38(7), 1540â1543.

Authors 2

R. Stephen Berry (first)
Curt W. Reimann (additional)

References 19 Referenced 329

10.1063/1.1732238 / J. Chem. Phys. (1961)
10.1063/1.1733000 / J. Chem. Phys. (1962)
{'key': '2024020821301109300_r3'}
10.1021/cr60212a004 / Chem. Rev. (1961)
10.1103/PhysRev.73.1002 / Phys. Rev. (1948)
{'key': '2024020821301109300_r6'}
10.1103/PhysRev.126.1482 / Phys. Rev. (1962)
10.1103/PhysRev.125.1602 / Phys. Rev. (1962)
10.1103/PhysRev.111.504 / Phys. Rev. (1958)
10.1063/1.1731714 / J. Chem. Phys. (1961)
10.1063/1.1731143 / J. Chem. Phys. (1960)
10.1063/1.1732583 / J. Chem. Phys. (1962)
10.1103/PhysRev.127.830 / Phys. Rev. (1962)
10.1063/1.1744273 / J. Chem. Phys. (1958)
{'key': '2024020821301109300_r15', 'first-page': '2189', 'volume': '34', 'year': '1961', 'journal-title': 'J. Chem. Phys.'} / J. Chem. Phys. (1961)
{'key': '2024020821301109300_r16', 'first-page': '680', 'volume': '105', 'year': '1955', 'journal-title': 'Dokl. Akad. Nauk S.S.S.R.'} / Dokl. Akad. Nauk S.S.S.R. (1955)
10.1103/PhysRev.118.626 / Phys. Rev. (1960)
10.1063/1.1733265 / J. Chem. Phys. (1962)
{'key': '2024020821301109300_r19'}

Dates

Type	When
Created	20 years, 7 months ago (Jan. 9, 2005, 1:59 a.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 4:30 p.m.)
Indexed	2 months, 1 week ago (June 20, 2025, 8:06 a.m.)
Issued	62 years, 5 months ago (April 1, 1963)
Published	62 years, 5 months ago (April 1, 1963)
Published Print	62 years, 5 months ago (April 1, 1963)

Funders 0

None

BibTeX

@article{Berry_1963, title={Absorption Spectrum of Gaseous F- and Electron Affinities of the Halogen Atoms}, volume={38}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1776916}, DOI={10.1063/1.1776916}, number={7}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Berry, R. Stephen and Reimann, Curt W.}, year={1963}, month=apr, pages={1540–1543} }

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