DOI: 10.1063/1.1750371. The Near Ultraviolet Absorption of Substituted Benzenes

The Near Ultraviolet Absorption of Substituted Benzenes

10.1063/1.1750371

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The intensification of ultraviolet absorption in substituted over unsubstituted benzene is here attributed to the destruction of the sixfold symmetry of the benzene by the partial migration of an electron to the ring or out of it. Toluene, aniline, phenol, and fluorobenzene are treated. The electric moment produced by a migration of an electron from the radical into the benzene ring is calculated by the method of antisymmetric molecular orbitals and the extent of migration by a minimum condition. The results are in agreement with empirical data. It is concluded that a radical will produce a large intensification of the absorption if it has a low ionization potential, a pair of nonbonding P electrons, and a not too large ring-radical distance. On this basis the SH group is predicted to be very effective.

Authors 1

A. L. Sklar (first)

References 28 Referenced 86

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10.1063/1.1750419 / J. Chem. Phys. (1939)
{'key': '2024020812062834400_r3'}
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10.1103/PhysRev.36.51 / Phys. Rev. (1930)
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Dates

Type	When
Created	20 years, 3 months ago (April 25, 2005, 9:30 a.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 7:09 a.m.)
Indexed	1 month, 3 weeks ago (July 2, 2025, 11:58 a.m.)
Issued	85 years, 9 months ago (Nov. 1, 1939)
Published	85 years, 9 months ago (Nov. 1, 1939)
Published Print	85 years, 9 months ago (Nov. 1, 1939)

Funders 0

None

BibTeX

@article{Sklar_1939, title={The Near Ultraviolet Absorption of Substituted Benzenes}, volume={7}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1750371}, DOI={10.1063/1.1750371}, number={11}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Sklar, A. L.}, year={1939}, month=nov, pages={984–993} }

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