DOI: 10.1063/1.1750296. The Entropy of Ethyl Alcohol from Molecular Data and the Equilibrium in the Hydration of Ethylene

The Entropy of Ethyl Alcohol from Molecular Data and the Equilibrium in the Hydration of Ethylene

10.1063/1.1750296

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The entropy and free energy of ethyl alcohol gas have been calculated from the molecular data at several temperatures on the basis of (a) free internal rotation, (b) restricted rotation (with potentials; about C–C bond=3000, C–O bond=10,000 calories). The latter values are in perfect agreement with those from the third law and from the equilibrium data on the hydration of ethylene.

Bibliography

Schumann, S. C., & Aston, J. G. (1938). The Entropy of Ethyl Alcohol from Molecular Data and the Equilibrium in the Hydration of Ethylene. The Journal of Chemical Physics, 6(8), 480â484.

Authors 2

S. C. Schumann (first)
John G. Aston (additional)

References 32 Referenced 25

{'key': '2024020811545109100_r1', 'first-page': '391', 'volume': '4', 'year': '1936', 'journal-title': 'J. Chem. Phys.'} / J. Chem. Phys. (1936)
10.1021/ja01303a002 / J. Am. Chem. Soc. (1936)
10.1063/1.1749890 / J. Chem. Phys. (1936)
{'key': '2024020811545109100_r3', 'first-page': '749', 'volume': '4', 'year': '1936', 'journal-title': 'J. Chem. Phys.'} / J. Chem. Phys. (1936)
10.1021/ja01281a014 / J. Am. Chem. Soc. (1937)
10.1021/ja01288a054 / J. Am. Chem. Soc. (1937)
{'key': '2024020811545109100_r5', 'first-page': '494', 'volume': '60', 'year': '1938', 'journal-title': 'J. Am. Chem. Soc.'} / J. Am. Chem. Soc. (1938)
10.1063/1.1750053 / J. Chem. Phys. (1937)
10.1063/1.1750118 / J. Chem. Phys. (1938)
10.1021/ja01378a016 / J. Am. Chem. Soc. (1929)
10.6028/jres.006.054 / Nat. Bur. Stand. J. Research (1931)
{'key': '2024020811545109100_r10'}
{'key': '2024020811545109100_r11'}
10.1007/BF01341323 / Zeits. f. Physik. (1934)
{'key': '2024020811545109100_r12a', 'first-page': '607', 'volume': '90', 'year': '1934'} (1934)
10.1063/1.1749302 / J. Chem. Phys. (1933)
{'key': '2024020811545109100_r13', 'first-page': '40', 'volume': 'B30', 'year': '1935', 'journal-title': 'Zeits. f. Physik. Chemie'} / Zeits. f. Physik. Chemie (1935)
10.1063/1.1750059 / J. Chem. Phys. (1937)
10.1063/1.1749684 / J. Chem. Phys. (1935)
10.1063/1.1749835 / J. Chem. Phys. (1936)
10.1063/1.1750058 / J. Chem. Phys. (1937)
{'key': '2024020811545109100_r18', 'first-page': '205T', 'volume': '53', 'year': '1934', 'journal-title': 'J. Soc. Chem. Ind.'} / J. Soc. Chem. Ind. (1934)
{'key': '2024020811545109100_r19', 'first-page': '279T', 'volume': '56', 'year': '1937', 'journal-title': 'J. Soc. Chem. Ind.'} / J. Soc. Chem. Ind. (1937)
10.1021/ie50325a004 / Ind. Eng. Chem. (1937)
10.1063/1.1749422 / J. Chem. Phys. (1934)
10.1021/ja01286a031 / J. Am. Chem. Soc. (1937)
10.1021/ja01282a039 / J. Am. Chem. Soc. (1937)
10.6028/jres.006.001 / Nat. Bur. Stand. J. Research (1931)
10.6028/jres.013.013 / Nat. Bur. Stand. J. Research (1934)
10.1021/ja01298a023 / J. Am. Chem. Soc. (1936)
10.6028/jres.019.017 / Nat. Bur. Stand. J. Research (1937)
10.1021/ie50331a025 / Ind. Eng. Chem. (1937)

Dates

Type	When
Created	20 years, 7 months ago (Jan. 9, 2005, 6:30 a.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 6:55 a.m.)
Indexed	1 year, 6 months ago (Feb. 9, 2024, 1:50 a.m.)
Issued	87 years ago (Aug. 1, 1938)
Published	87 years ago (Aug. 1, 1938)
Published Print	87 years ago (Aug. 1, 1938)

Funders 0

None

BibTeX

@article{Schumann_1938, title={The Entropy of Ethyl Alcohol from Molecular Data and the Equilibrium in the Hydration of Ethylene}, volume={6}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1750296}, DOI={10.1063/1.1750296}, number={8}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Schumann, S. C. and Aston, John G.}, year={1938}, month=aug, pages={480–484} }

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