DOI: 10.1063/1.1749657. Statistical Mechanics of Fluid Mixtures

10.1063/1.1749657

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Expressions for the chemical potentials of the components of gas mixtures and liquid solutions are obtained in terms of relatively simple integrals in the configuration spaces of molecular pairs. The molecular pair distribution functions appearing in these integrals are investigated in some detail, in their dependence upon the composition and density of the fluid. The equation of state of a real gas mixture is discussed, and an approximate molecular pair distribution function, typical of dense fluids, is calculated. Applications of the method to the theory of solutions will be the subject of a later article.

Bibliography

Kirkwood, J. G. (1935). Statistical Mechanics of Fluid Mixtures. The Journal of Chemical Physics, 3(5), 300â313.

Authors 1

John G. Kirkwood (first)

References 14 Referenced 2,993

10.1103/PhysRev.40.749 / Phys. Rev. (1932)
10.1103/PhysRev.41.79 / Phys. Rev. (1932)
10.1103/PhysRev.44.31 / Phys. Rev. (1933)
10.1063/1.1749334 / J. Chem. Phys. (1933)
10.1021/cr60044a006 / Chem. Rev. (1933)
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{'key': '2024020811273116200_r5', 'first-page': '222', 'volume': '11', 'year': '1930', 'journal-title': 'Zeits. f. Physik. Chemie'} / Zeits. f. Physik. Chemie (1930)
10.1021/cr60044a006 / Chem. Rev. (1933)
{'key': '2024020811273116200_r7', 'first-page': '184', 'volume': '41', 'year': '1927', 'journal-title': 'Zeits. f. Physik'} / Zeits. f. Physik (1927)
{'key': '2024020811273116200_r7a', 'first-page': '797', 'volume': '31', 'year': '1930', 'journal-title': 'Physik. Zeits.'} / Physik. Zeits. (1930)
10.1017/S0305004100011191 / Proc. Camb. Phil. Soc. (1927)
{'key': '2024020811273116200_r8a'}

Dates

Type	When
Created	20 years, 9 months ago (Nov. 3, 2004, 6:48 p.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 6:28 a.m.)
Indexed	3 days, 6 hours ago (Aug. 20, 2025, 9:14 a.m.)
Issued	90 years, 3 months ago (May 1, 1935)
Published	90 years, 3 months ago (May 1, 1935)
Published Print	90 years, 3 months ago (May 1, 1935)

Funders 0

None

BibTeX

@article{Kirkwood_1935, title={Statistical Mechanics of Fluid Mixtures}, volume={3}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1749657}, DOI={10.1063/1.1749657}, number={5}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Kirkwood, John G.}, year={1935}, month=may, pages={300–313} }

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