Abstract
The microwave spectra of C212H4O, C12C13H4O, C212D4O, C212H4S32, C212H4S34, and C212D4S32 have been determined. For each isotopic species three moments of inertia are obtained. From the 9 moments of inertia for each compound, a set of ``effective'' bond distances and angles (5 in number) have been selected. These ``effective'' bond distances are all self consistent to 0.002A or better. A brief discussion of the resulting structure is given. The dipole moments of C2H4O and C2H4S were determined from the magnitude of the Stark splitting.
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Dates
Type | When |
---|---|
Created | 20 years, 7 months ago (Jan. 9, 2005, 7:54 a.m.) |
Deposited | 1 year, 6 months ago (Feb. 8, 2024, 9:05 a.m.) |
Indexed | 53 minutes ago (Sept. 4, 2025, 2:56 a.m.) |
Issued | 74 years, 3 months ago (June 1, 1951) |
Published | 74 years, 3 months ago (June 1, 1951) |
Published Print | 74 years, 3 months ago (June 1, 1951) |
@article{Cunningham_1951, title={The Microwave Spectra, Structure, and Dipole Moments of Ethylene Oxide and Ethylene Sulfide}, volume={19}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1748331}, DOI={10.1063/1.1748331}, number={6}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Cunningham, George L. and Boyd, A. W. and Myers, Rollie J. and Gwinn, William D. and Le Van, W. I.}, year={1951}, month=jun, pages={676–685} }