DOI: 10.1063/1.1748127. The Spherical Interface. I. Thermodynamics

The Spherical Interface. I. Thermodynamics

10.1063/1.1748127

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

An extension of the Gibbs thermodynamic theory of spherical interfaces leads to generalized forms for the Kelvin relation and the Gibbs adsorption equation. Quantities of physical interest are calculated in terms of the particular dividing surface making the superficial density of matter vanish, frequently more convenient than the surface of tension. An expression is proposed for the work required to form a droplet which is not in equilibrium with the surrounding vapor.

Bibliography

Buff, F. P. (1951). The Spherical Interface. I. Thermodynamics. The Journal of Chemical Physics, 19(12), 1591â1594.

Authors 1

Frank P. Buff (first)

References 12 Referenced 166

10.1063/1.1747829 / J. Chem. Phys. (1950)
{'key': '2024020814132667000_r2'}
{'key': '2024020814132667000_r3'}
{'key': '2024020814132667000_r4'}
10.1063/1.1747247 / J. Chem. Phys. (1949)
10.1063/1.1747660 / J. Chem. Phys. (1950)
10.1063/1.1748263 / J. Chem. Phys. (1951)
{'key': '2024020814132667000_r8', 'first-page': '719', 'volume': '24', 'year': '1935', 'journal-title': 'Z. Physik'} / Z. Physik (1935)
{'key': '2024020814132667000_r9'}
10.1063/1.1747248 / J. Chem. Phys. (1949)
10.1063/1.1746994 / J. Chem. Phys. (1948)
{'key': '2024020814132667000_r12'}

Dates

Type	When
Created	20 years, 7 months ago (Jan. 9, 2005, 7:54 a.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 9:23 a.m.)
Indexed	1 week ago (Aug. 23, 2025, 9:55 p.m.)
Issued	73 years, 8 months ago (Dec. 1, 1951)
Published	73 years, 8 months ago (Dec. 1, 1951)
Published Print	73 years, 8 months ago (Dec. 1, 1951)

Funders 0

None

BibTeX

@article{Buff_1951, title={The Spherical Interface. I. Thermodynamics}, volume={19}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1748127}, DOI={10.1063/1.1748127}, number={12}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Buff, Frank P.}, year={1951}, month=dec, pages={1591–1594} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        8,
        24
      ]
    ],
    "date-time": "2025-08-24T01:55:22Z",
    "timestamp": 1756000522043
  },
  "reference-count": 12,
  "publisher": "AIP Publishing",
  "issue": "12",
  "content-domain": {
    "domain": [
      "pubs.aip.org"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        1951,
        12,
        1
      ]
    ]
  },
  "abstract": "<jats:p>An extension of the Gibbs thermodynamic theory of spherical interfaces leads to generalized forms for the Kelvin relation and the Gibbs adsorption equation. Quantities of physical interest are calculated in terms of the particular dividing surface making the superficial density of matter vanish, frequently more convenient than the surface of tension. An expression is proposed for the work required to form a droplet which is not in equilibrium with the surrounding vapor.</jats:p>",
  "DOI": "10.1063/1.1748127",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2005,
        1,
        9
      ]
    ],
    "date-time": "2005-01-09T12:54:08Z",
    "timestamp": 1105275248000
  },
  "page": "1591-1594",
  "update-policy": "http://dx.doi.org/10.1063/aip-crossmark-policy-page",
  "source": "Crossref",
  "is-referenced-by-count": 166,
  "title": "The Spherical Interface. I. Thermodynamics",
  "prefix": "10.1063",
  "volume": "19",
  "author": [
    {
      "given": "Frank P.",
      "family": "Buff",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Chemistry Department, University of Rochester, Rochester, New York"
        }
      ]
    }
  ],
  "member": "317",
  "reference": [
    {
      "key": "2024020814132667000_r1",
      "doi-asserted-by": "crossref",
      "first-page": "991",
      "DOI": "10.1063/1.1747829",
      "volume": "18",
      "year": "1950",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020814132667000_r2"
    },
    {
      "key": "2024020814132667000_r3"
    },
    {
      "key": "2024020814132667000_r4"
    },
    {
      "key": "2024020814132667000_r5",
      "doi-asserted-by": "crossref",
      "first-page": "333",
      "DOI": "10.1063/1.1747247",
      "volume": "17",
      "year": "1949",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020814132667000_r6",
      "doi-asserted-by": "crossref",
      "first-page": "449",
      "DOI": "10.1063/1.1747660",
      "volume": "18",
      "year": "1950",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020814132667000_r7",
      "doi-asserted-by": "crossref",
      "first-page": "506",
      "DOI": "10.1063/1.1748263",
      "volume": "19",
      "year": "1951",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020814132667000_r8",
      "first-page": "719",
      "volume": "24",
      "year": "1935",
      "journal-title": "Z. Physik"
    },
    {
      "key": "2024020814132667000_r9"
    },
    {
      "key": "2024020814132667000_r10",
      "doi-asserted-by": "crossref",
      "first-page": "338",
      "DOI": "10.1063/1.1747248",
      "volume": "17",
      "year": "1949",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020814132667000_r11",
      "doi-asserted-by": "crossref",
      "first-page": "758",
      "DOI": "10.1063/1.1746994",
      "volume": "16",
      "year": "1948",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020814132667000_r12"
    }
  ],
  "container-title": "The Journal of Chemical Physics",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/19/12/1591/18799777/1591_1_online.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/19/12/1591/18799777/1591_1_online.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        2,
        8
      ]
    ],
    "date-time": "2024-02-08T14:23:04Z",
    "timestamp": 1707402184000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.aip.org/jcp/article/19/12/1591/201945/The-Spherical-Interface-I-Thermodynamics"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1951,
        12,
        1
      ]
    ]
  },
  "references-count": 12,
  "journal-issue": {
    "issue": "12",
    "published-print": {
      "date-parts": [
        [
          1951,
          12,
          1
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.1748127",
  "relation": {},
  "ISSN": [
    "0021-9606",
    "1089-7690"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        1951,
        12
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        1951,
        12,
        1
      ]
    ]
  }
}