DOI: 10.1063/1.1747846. The Vibrational Spectra and Structure of Inorganic Molecules. II. Sulfur S8, Sulfur Chloride S2Cl2, Phosphorous P4

The Vibrational Spectra and Structure of Inorganic Molecules. II. Sulfur S8, Sulfur Chloride S2Cl2, Phosphorous P4

10.1063/1.1747846

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The infra-red spectra from 2–25μ have been obtained for S8 as solid and in CS2 solution; for S2Cl2 as liquid and in CS2 solution; and for P4 in CS2 solution. A satisfactory assignment of the Raman and infra-red spectrum of S8 has been made on the basis of D4d symmetry. The spectrum and valence force calculations are consistent with the C2 structure for S2Cl2, and together with the electron diffraction data exclude the C2v form. The vibrational spectrum of P4 is interpreted unequivocally on the basis of the tetrahedral structure (Td).

Bibliography

Bernstein, H. J., & Powling, J. (1950). The Vibrational Spectra and Structure of Inorganic Molecules. II. Sulfur S8, Sulfur Chloride S2Cl2, Phosphorous P4. The Journal of Chemical Physics, 18(8), 1018â1023.

Authors 2

H. J. Bernstein (first)
J. Powling (additional)

References 13 Referenced 58

10.1063/1.1749557 / J. Chem. Phys. (1935)
{'key': '2024020813503612500_r2', 'first-page': '101', 'volume': '8A', 'year': '1938', 'journal-title': 'Proc. Ind. Acad. Sci.'} / Proc. Ind. Acad. Sci. (1938)
{'key': '2024020813503612500_r3'}
{'key': '2024020813503612500_r4'}
{'key': '2024020813503612500_r5', 'first-page': '702', 'volume': '60', 'year': '1941', 'journal-title': 'Rec. Trav. Chim. Pays-Bas'} / Rec. Trav. Chim. Pays-Bas (1941)
{'key': '2024020813503612500_r6', 'first-page': '275', 'volume': '6', 'year': '1931', 'journal-title': 'Ind. J. Phys.'} / Ind. J. Phys. (1931)
10.1021/ja01277a023 / J. Am. Chem. Soc. (1938)
{'key': '2024020813503612500_r8'}
{'key': '2024020813503612500_r9', 'first-page': '220', 'volume': '32', 'year': '1937', 'journal-title': 'Sci. Pap. Phys. Chem. Res. Tokyo'} / Sci. Pap. Phys. Chem. Res. Tokyo (1937)
{'key': '2024020813503612500_r10', 'first-page': '260', 'volume': '2A', 'year': '1935', 'journal-title': 'Proc. Ind. Acad. Sci.'} / Proc. Ind. Acad. Sci. (1935)
{'key': '2024020813503612500_r10a', 'first-page': '345', 'volume': '4A', 'year': '1936', 'journal-title': 'Proc. Indian Acad. Sci., Sect. A'} / Proc. Indian Acad. Sci., Sect. A (1936)
{'key': '2024020813503612500_r11', 'first-page': '119', 'volume': '8A', 'year': '1938', 'journal-title': 'Proc. Ind. Acad. Sci.'} / Proc. Ind. Acad. Sci. (1938)
10.1063/1.1749580 / J. Chem. Phys. (1935)

Dates

Type	When
Created	20 years, 7 months ago (Jan. 9, 2005, 7:19 a.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 8:50 a.m.)
Indexed	1 month, 3 weeks ago (July 2, 2025, 2:12 p.m.)
Issued	75 years ago (Aug. 1, 1950)
Published	75 years ago (Aug. 1, 1950)
Published Print	75 years ago (Aug. 1, 1950)

Funders 0

None

BibTeX

@article{Bernstein_1950, title={The Vibrational Spectra and Structure of Inorganic Molecules. II. Sulfur S8, Sulfur Chloride S2Cl2, Phosphorous P4}, volume={18}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1747846}, DOI={10.1063/1.1747846}, number={8}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Bernstein, H. J. and Powling, J.}, year={1950}, month=aug, pages={1018–1023} }

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