DOI: 10.1063/1.1747660. On the Thermodynamic Relation between Surface Tension and Curvature

On the Thermodynamic Relation between Surface Tension and Curvature

10.1063/1.1747660

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

From the Gibbs theory of surface tension general equations are deduced for the change of surface tension with curvature in the system having an arbitrary number of components but no insoluble surface film. For the special case that the surface layer is spherical, the equations are shown to be reducible, by an appropriate choice of auxiliary Gibbs surfaces, to a simple form identical with that recently found by Tolman for the system of one component. Some of the consequences of physical interest following from the equation for the spherical surface layer are pointed out.

Bibliography

Koenig, F. O. (1950). On the Thermodynamic Relation between Surface Tension and Curvature. The Journal of Chemical Physics, 18(4), 449â459.

Authors 1

Frederick O. Koenig (first)

References 13 Referenced 132

10.1063/1.1747247 / J. Chem. Phys. (1949)
{'key': '2024020813285521400_r2'}
{'key': '2024020813285521400_r3', 'first-page': '397', 'volume': '36', 'year': '1939', 'journal-title': 'Trans. Faraday Soc.'} / Trans. Faraday Soc. (1939)
{'key': '2024020813285521400_r4'}
{'key': '2024020813285521400_r5'}
10.1063/1.1746994 / J. Chem. Phys. (1948)
{'key': '2024020813285521400_r6'}
{'key': '2024020813285521400_r7'}
{'key': '2024020813285521400_r8'}
{'key': '2024020813285521400_r8a', 'first-page': '218', 'volume': 'A139', 'year': '1933', 'journal-title': 'Proc. Roy. Soc.'} / Proc. Roy. Soc. (1933)
{'key': '2024020813285521400_r9'}
10.1063/1.1747204 / J. Chem. Phys. (1949)
10.1063/1.1747248 / J. Chem. Phys. (1949)

Dates

Type	When
Created	20 years, 7 months ago (Jan. 9, 2005, 7:19 a.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 8:29 a.m.)
Indexed	3 months, 1 week ago (May 28, 2025, 3:26 a.m.)
Issued	75 years, 5 months ago (April 1, 1950)
Published	75 years, 5 months ago (April 1, 1950)
Published Print	75 years, 5 months ago (April 1, 1950)

Funders 0

None

BibTeX

@article{Koenig_1950, title={On the Thermodynamic Relation between Surface Tension and Curvature}, volume={18}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1747660}, DOI={10.1063/1.1747660}, number={4}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Koenig, Frederick O.}, year={1950}, month=apr, pages={449–459} }

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