DOI: 10.1063/1.1747147. Electrochemical Thermodynamics and Kinetics of Hydrogen Overvoltage

Electrochemical Thermodynamics and Kinetics of Hydrogen Overvoltage

10.1063/1.1747147

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The problem of hydrogen overvoltage is attacked by a method making systematic use of chemical and electrochemical potentials. More precise formulas are thereby obtained than in previous theories and a more definite interpretation of the transfer coefficient of Erdey-Grúz and Volmer is arrived at. The Tafel empirical equation is discussed and the existence, in some cases, of several Tafel regions is considered. Activation free energies, energies, and entropies for the discharge process are calculated and the mechanism involving formation of atomic hydrogen is shown to be entirely plausible.

Bibliography

Van Rysselberghe, P. (1949). Electrochemical Thermodynamics and Kinetics of Hydrogen Overvoltage. The Journal of Chemical Physics, 17(12), 1226â1231.

Authors 1

Pierre Van Rysselberghe (first)

References 23 Referenced 9

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10.1039/tf9423800474 / Trans. Faraday Soc. (1942)
{'key': '2024020813234066200_r4'}
{'key': '2024020813234066200_r5'}
{'key': '2024020813234066200_r6', 'first-page': '203', 'volume': '150', 'year': '1930', 'journal-title': 'Zeits. f. Physik. Chemie'} / Zeits. f. Physik. Chemie (1930)
{'key': '2024020813234066200_r6a', 'first-page': '87', 'volume': '61', 'year': '1948', 'journal-title': 'Doklady Akad. Nauk S.S.S.R.'} / Doklady Akad. Nauk S.S.S.R. (1948)
{'key': '2024020813234066200_r6b', 'first-page': '48', 'volume': '43', 'year': '1948', 'journal-title': 'Chem. Abs.'} / Chem. Abs. (1948)
{'key': '2024020813234066200_r7', 'first-page': '53', 'volume': '162', 'year': '1932', 'journal-title': 'Zeits. f. Physik. Chemie'} / Zeits. f. Physik. Chemie (1932)
{'key': '2024020813234066200_r7a'}
{'key': '2024020813234066200_r8'}
{'key': '2024020813234066200_r9', 'first-page': '86', 'volume': 'I', 'year': '1947', 'journal-title': 'Faraday Soc. Discussion'} / Faraday Soc. Discussion (1947)
10.1063/1.1750831 / J. Chem. Phys. (1941)
{'key': '2024020813234066200_r11', 'first-page': '116', 'volume': '160', 'year': '1932', 'journal-title': 'Zeits. f. Physik. Chemie'} / Zeits. f. Physik. Chemie (1932)
{'key': '2024020813234066200_r11a', 'first-page': '121', 'volume': '164', 'year': '1933'} (1933)
{'key': '2024020813234066200_r11b'}
{'key': '2024020813234066200_r12'}
{'key': '2024020813234066200_r13', 'first-page': '72', 'volume': 'I', 'year': '1947', 'journal-title': 'Faraday Soc. Discussion'} / Faraday Soc. Discussion (1947)
{'key': '2024020813234066200_r14', 'first-page': '90', 'volume': '35', 'year': '1938', 'journal-title': 'Ann. Rep. on Progress Chem. (Chem. Soc. London)'} / Ann. Rep. on Progress Chem. (Chem. Soc. London) (1938)
{'key': '2024020813234066200_r15'}
{'key': '2024020813234066200_r16'}
10.1021/cr60136a005 / Chem. Rev. (1948)
{'key': '2024020813234066200_r18', 'first-page': '903', 'volume': '13', 'year': '1942', 'journal-title': 'Atti Reale Accad. Italia. Mem. Classe Sci. Fis. Mat. e Nat.'} / Atti Reale Accad. Italia. Mem. Classe Sci. Fis. Mat. e Nat. (1942)

Dates

Type	When
Created	20 years, 7 months ago (Jan. 9, 2005, 7:07 a.m.)
Deposited	1 year, 6 months ago (Feb. 8, 2024, 8:24 a.m.)
Indexed	1 year, 6 months ago (Feb. 8, 2024, 2:27 p.m.)
Issued	75 years, 9 months ago (Dec. 1, 1949)
Published	75 years, 9 months ago (Dec. 1, 1949)
Published Print	75 years, 9 months ago (Dec. 1, 1949)

Funders 0

None

BibTeX

@article{Van_Rysselberghe_1949, title={Electrochemical Thermodynamics and Kinetics of Hydrogen Overvoltage}, volume={17}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.1747147}, DOI={10.1063/1.1747147}, number={12}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Van Rysselberghe, Pierre}, year={1949}, month=dec, pages={1226–1231} }

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